Art

J-GLOBAL ID：201302248676254087   Reference number：13A1772744

A Stable Silene Substituted by Strong π-Donors at the Silicon Center

シリコン中心での強いπ-供与体により置換された安定シレン

Author (7)： NAKATA Norio (Univ. Toulouse, Toulouse, FRA) ,  RODRIGUEZ Ricardo (Univ. Toulouse, Toulouse, FRA) ,  TROADEC Thibault (Univ. Toulouse, Toulouse, FRA) ,  SAFFON-MERCERON Nathalie (Univ. Toulouse, Toulouse, FRA) ,  SOTIROPOULOS Jean-Marc (Univ. Pau et des Pays de l’Adour, Pau, FRA) ,  BACEIREDO Antoine (Univ. Toulouse, Toulouse, FRA) ,  KATO Tsuyoshi (Univ. Toulouse, Toulouse, FRA)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 52  Issue： 41  Page： 10840-10844  Publication year： 2013 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *silylene ,  *cycloaddition ,  *platinum complex ,  ring-opening reaction ,  *substituent effect ,  HOMO ,  energy level ,  organosilicon compound ,  silylamines ,  silylene complex

JST classification (1)： Organosilicon compounds  (CF08030C)

Substance index (7)： Methyl trifluoromethanesulfonate ,  N-(2,6-Diisopropylphenyl)-3-[1,3-di-tert-butyl-2-(2,3-diphenyl-1-silacyclopropane-2-yl)-4,4-dimethyl-1,3-diaza-2-phospha(V)-4-silacyclobutane-2-ylidene]bicyclo[2.2.1]heptane-2-imine ,  1-(2,6-Diisopropylphenyl)-2-benzylidene-3-phenyl-1′,3′-di-tert-butyl-4′,4′-dimethyl-5,8-methano-1,1′,3′-triaza-4-phospha-2,4′-disila-1,2,5,6,7,8-hexahydrospiro[naphthalene-4,2′-cyclobutane] ,  1-Methyl-2-benzylidene-1-aza-2-silacyclohexane ,  1-Methyl-2-benzylidene-1-aza-4-phospha-2-silacyclohexane-3-ene ,  Trifluoromethanesulfonic acid 1-(2,6-diisopropylphenyl)-2-[(R)-1-phenylethyl]-3-phenyl-1′,3′-di-tert-butyl-4′,4′-dimethyl-5,8-methano-1,1′,3′-triaza-4-phospha-2,4′-disila-1,2,5,6,7,8-hexahydrospiro[naphthalene-4,2′-cyclobutane]-2-yl ester ,  α-Phenyl-1-(2,6-diisopropylphenyl)-2-hydroxy-3-phenyl-1′,3′-di-tert-butyl-4′,4′-dimethyl-5,8-methano-1,1′,3′-triaza-4-phospha-2,4′-disila-1,2,5,6,7,8-hexahydrospiro[naphthalene-4,2′-cyclobutane]-2-acetic acid lactone

Terms in the title (4)： シリコン ,  供与体 ,  置換 ,  シレン