Art

J-GLOBAL ID：201302285280844895   Reference number：13A1617662

Lewis Acid-Promoted Cyclization Reactions of Alkenyl Ethenetricarboxylates: Stereoselective Synthesis of 2-Oxotetrahydrofurans and 2-Oxopyrrolidines

アルケニルエテントリカルボキシラート類のLewis酸促進環化反応:2-オキソテトラヒドロフラン類および2-オキソピロリジン類の立体特異性合成

Author (5)： YAMAZAKI Shoko (Nara Univ. Education, Nara, JPN) ,  FUJINAMI Ken (Nara Univ. Education, Nara, JPN) ,  MAITOKO Yuki (Nara Univ. Education, Nara, JPN) ,  UEDA Khota (Nara Univ. Education, Nara, JPN) ,  KAKIUCHI Kiyomi (Nara Inst. of Sci. and Technol. (NAIST), Nara, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 78  Issue： 17  Page： 8405-8416  Publication year： Sep. 06, 2013 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： Lewis acid ,  *cyclization reaction ,  *cyclic ether ,  *oxygen heterocyclic compound ,  *nitrogen heterocyclic compound ,  chemical synthesis ,  stereospecific reaction ,  *NOESY ,  molecular structure ,  Lewis acid catalyst ,  catalytic reaction ,  density functional method ,  Gibbs free energy ,  reaction intermediate ,  reaction mechanism ,  *Pyrrolidines ,  *tetrahydrofuran derivative
Semi thesaurus term： *tetrahydrofurans

JST classification (2)： Cyclization reaction,ring-opening reaction  (CF02050I) ,  Heterocyclic compounds in general  (CF07010Z)

Substance index (15)： 2-(2-Oxo-4-chloromethyltetrahydrofuran-3-yl)malonic acid diethyl ester ,  2-(2-Oxo-4-bromomethyltetrahydrofuran-3-yl)malonic acid diethyl ester ,  2-(2-Oxo-4-(1-chloroethyl)tetrahydrofuran-3-yl)malonic acid diethyl ester ,  2-(2-Oxo-4-(1-chloroethyl)tetrahydrofuran-3-yl)malonic acid dimethyl ester ,  2-(1-Methyl-2-oxo-4-chloromethyl-3-pyrrolidinyl)malonic acid diethyl ester ,  2-(1-Methyl-2-oxo-4-bromomethyl-3-pyrrolidinyl)malonic acid diethyl ester ,  2-(1-Methyl-2-oxo-4-iodomethyl-3-pyrrolidinyl)malonic acid diethyl ester ,  2-(1-Allyl-2-oxo-4-chloromethyl-3-pyrrolidinyl)malonic acid diethyl ester ,  2-(1-Allyl-2-oxo-4-bromomethyl-3-pyrrolidinyl)malonic acid diethyl ester ,  2-(1-Allyl-2-oxo-4-iodomethyl-3-pyrrolidinyl)malonic acid diethyl ester ,  2-(1-Propyl-2-oxo-4-chloromethyl-3-pyrrolidinyl)malonic acid diethyl ester ,  2-(1-Propyl-2-oxo-4-bromomethyl-3-pyrrolidinyl)malonic acid diethyl ester ,  2-(1-Propyl-2-oxo-4-iodomethyl-3-pyrrolidinyl)malonic acid diethyl ester ,  2-(2-Oxo-4-methyltetrahydrofuran-3-yl)malonic acid diethyl ester ,  2-(1-Methyl-2-oxo-4-methyl-3-pyrrolidinyl)malonic acid diethyl ester

Terms in the title (6)： Lewis酸 ,  促進 ,  環化反応 ,  テトラヒドロフラン類 ,  2-オキソピロリジン ,  立体特異性合成