Art

J-GLOBAL ID：201302295897328342   Reference number：13A0316929

Remote C-H bond functionalization of androstane C-ring: C12-amination

アンドロスタンC-環の遠隔C-H結合官能化: C12-アミノ化

Author (5)： YAMASHITA Shuji (Dep. of Chemistry, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN) ,  HIMURO Masafumi (Dep. of Chemistry, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN) ,  HAYASHI Yujiro (Dep. of Chemistry, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN) ,  HIRAMA Masahiro (Dep. of Chemistry, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN) ,  HIRAMA Masahiro (Res. and Analytical Center for Giant Molecules, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 54  Issue： 10  Page： 1307-1308  Publication year： Mar. 06, 2013 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： C-H bond ,  *functionalization ,  *steroid ,  *Amination ,  metabolite ,  male sex hormone ,  adrenal sex hormone ,  alicyclic alcohol ,  alicyclic ketone ,  secondary alcohol ,  *Androstanes

JST classification (1)： Steroids  (CF10040O)

Substance index (7)： 12β-Amino-3β-(triisopropylsiloxy)-5α-androstane-17β-ol ,  17β-Hydroxy-3β-(triisopropylsiloxy)-5α-androstane-12-one ,  3β-(Triisopropylsiloxy)-12β,17β-(iminosulfonyloxy)-5α-androstane ,  3β-(Triisopropylsiloxy)-17β-(sulfamoyloxy)-5α-androstane ,  3β-(Triisopropylsiloxy)-5α-androstane-12β,17β-diol ,  3β-(Triisopropylsiloxy)-5α-androsta-11-ene-17β-ol ,  Epiandrosterone

Terms in the title (5)： ロス ,  環 ,  C-H結合 ,  官能化 ,  アミノ化