Art

J-GLOBAL ID：201402232107473815   Reference number：14A0928727

Isolable Aryl-Substituted Silyl Radicals: Synthesis, Characterization, and Reactivity

単離可能なアリール置換シリルラジカル類 合成とキャラクタリゼーションおよび反応性

Author (3)： TAIRA Kanako (Univ. Tsukuba, Tsukuba, JPN) ,  ICHINOHE Masaaki (Univ. Tsukuba, Tsukuba, JPN) ,  SEKIGUCHI Akira (Univ. Tsukuba, Tsukuba, JPN)
Material： Chemistry - European Journal  (Chem Eur J)
Volume： 20  Issue： 30  Page： 9342-9348  Publication year： 2014 
JST Material Number： W0744A  ISSN： 0947-6539  CODEN： CEUJED  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *organosilicon compound ,  *radical ,  chemical synthesis ,  isolation(separation) ,  X-ray structural analysis ,  ESR ,  unpaired electron ,  silylene ,  reactivity ,  molecular structure ,  crystal structure
Semi thesaurus term： *シリルラジカル

JST classification (3)： Organosilicon compounds  (CF08030C) ,  EPR of organic compounds  (BM07024U) ,  Gevmetry of molecules in general  (BH05021S)

Substance index (15)： 1-(3,5-Di(tert-butyl)phenyl)-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane ,  [1,1,3,3-Tetra-tert-butyl-1,3-dimethyl-2-(3,5-di-tert-butylphenyl)trisilane-2-yl]radical ,  1-(4-(tert-Butyl)phenyl)-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane ,  1-(4-(tert-Butyl)phenyl)-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane-1-ylradical ,  1-(6-(1-Phenyl-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane-1-yl)-1,4-cyclohexene-3-ylidene)-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane ,  1-(Biphenyl-4-yl)-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane ,  1-(Biphenyl-4-yl)-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane-1-ylradical ,  1-Phenyl-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane ,  [Bis(di-tert-butylmethylsilyl)phenylsilyl]radical ,  1-Methoxy-1′-phenyl-[1,1′-(1,3-cyclohexene-2,5-diyl)bis(1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane)] ,  1-Methoxy-1′-phenyl-[1,1′-(1,4-cyclohexene-3,6-diyl)bis(1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane)] ,  1-Iodo-1-(3,5-di(tert-butyl)phenyl)-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane ,  1-Iodo-1-(4-(tert-butyl)phenyl)-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane ,  1-Iodo-1-(biphenyl-4-yl)-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane ,  1-Iodo-1-phenyl-1-(di(tert-butyl)methylsilyl)-2-methyl-2,2-di(tert-butyl)disilane

Terms in the title (4)： 単離 ,  アリール置換 ,  キャラクタリゼーション ,  反応性