Art

J-GLOBAL ID：201402239783120482   Reference number：14A0726643

Stereoselective Synthesis of the CDE Ring System of Antitumor Saponin Scillascilloside E-1

抗腫瘍性サポニン,シラシロシドE-1,のCDE環システムの立体選択的合成

Author (4)： AKAHORI Yoshihiro (Nagoya City Univ., Nagoya, JPN) ,  YAMAKOSHI Hiroyuki (Nagoya City Univ., Nagoya, JPN) ,  HASHIMOTO Shunichi (Hokkaido Univ., Sapporo, JPN) ,  NAKAMURA Seiichi (Nagoya City Univ., Nagoya, JPN)
Material： Organic Letters  (Org Lett)
Volume： 16  Issue： 7  Page： 2054-2057  Publication year： Apr. 04, 2014 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  *saponin ,  *oligosaccharide ,  *sterol ,  Claisen rearrangement ,  nitrile oxide ,  cycloaddition ,  Liliaceae ,  synthetic intermediate ,  spiro-compound ,  *oxygen heterocyclic compound ,  alicyclic compound
Semi thesaurus term： Ireland-Claisen rearrangement ,  Scilla scilloide

JST classification (2)： Glycosides  (CF10057O) ,  Furans  (CF07072V)

Substance index (9)： 3-Methyl-2-cyclohexene-1β-ol ,  (1S)-3aα,7aβ,3′α-Trimethyl-5′β-(tert-butyldiphenylsiloxymethyl)spiro[hydrindane-1,2′-oxolane]-4-one ,  (2S)-2-[(1S)-1-Methyl-2-cyclohexene-1α-yl]-3-methylene-5β-(tert-butyldiphenylsiloxymethyl)tetrahydrofuran-2β-acetonitrileoxide ,  (2S)-2-[(1S)-1-Methyl-2-cyclohexene-1α-yl]-3-methylene-5β-(tert-butyldiphenylsiloxymethyl)tetrahydrofuran-2β-carboxylic acid methyl ester ,  (4S)-4aα-Methyl-3′-methylene-5′β-(tert-butyldiphenylsiloxymethyl)-4a,5,6,7,7aα,7bα,4′,5′-octahydrospiro[indeno[1,7-cd]isoxazole-4(3H),2′(3′H)-furan] ,  (5S)-2-Diazo-3-oxo-5-hydroxy-6-(tert-butyldiphenylsiloxy)hexanoic acid (1R)-3-methyl-2-cyclohexene-1β-yl ester ,  (5S)-3-Methyl-5β-(tert-butyldiphenylsiloxymethyl)-4,5-dihydrofuran-2-carboxylic acid (R)-3-methyl-2-cyclohexene-1β-yl ester ,  Diazoacetic acid (1R)-3-methyl-2-cyclohexene-1β-yl ester ,  Scillascilloside E-1

Terms in the title (3)： 抗腫瘍性 ,  サポニン ,  立体選択的合成