Art

J-GLOBAL ID：201402283838969708   Reference number：14A0910794

N-Benzoyl- and N-Sulfonyl-1,5-benzodiazepines: Comparison of Their Atropisomeric and Conformational Properties

N-ベンゾイル-とN-スルホニル-1,5-ベンゾジアゼピン類:それらのアトロプ異性と立体配座特性の比較

Author (7)： YONEDA Tetsuya (Teikyo Univ., Tokyo, JPN) ,  TABATA Hidetsugu (Teikyo Univ., Tokyo, JPN) ,  NAKAGOMI Jun (Teikyo Univ., Tokyo, JPN) ,  TASAKA Tomohiko (Affinity Sci. Corp., Tokyo, JPN) ,  OSHITARI Tetsuta (Teikyo Univ., Tokyo, JPN) ,  TAKAHASHI Hideyo (Teikyo Univ., Tokyo, JPN) ,  NATSUGARI Hideaki (Teikyo Univ., Tokyo, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 79  Issue： 12  Page： 5717-5727  Publication year： Jun. 20, 2014 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： molecular structure ,  structure analysis ,  *nitrogen heterocyclic compound ,  *polynuclear aromatic compound ,  atropisomer ,  *atropisomerism ,  *benzoyl group ,  *group (radical) ,  substituent effect ,  stereochemistry ,  barrier ,  aromatic compound ,  organosulphur compound ,  density functional method ,  *sulfonyl group ,  Tosyl Compounds ,  conformational search ,  *Benzodiazepines ,  polymer structure
Semi thesaurus term： energy barrier ,  polymer structure

JST classification (4)： Seven-membered heterocyclic compounds  (CF07110I) ,  Stereochemistry of polymers  (CG02031G) ,  Crystal structure of organic compounds in general  (BK08001A) ,  Electronic structure of molecules  (BH05010Q)

Substance index (12)： 1-Methyl-5-benzoyl-4,5-dihydro-1H-1,5-benzodiazepine-2(3H)-one ,  5-Benzoyl-4,5-dihydro-1,6-dimethyl-1H-1,5-benzodiazepine-2(3H)-one ,  5-Benzoyl-1-methyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine ,  1,6-Dimethyl-5-benzoyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine ,  4,5-Dihydro-5-(4-methylphenylsulfonyl)-1-methyl-1H-1,5-benzodiazepine-2(3H)-one ,  1,6-Dimethyl-5-tosyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine-2-one ,  2,3,4,5-Tetrahydro-5-(4-methylphenylsulfonyl)-1-methyl-1H-1,5-benzodiazepine ,  1,6-Dimethyl-5-tosyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine ,  1,5-Dimethyl-3,4-dihydro-2H-1,5-benzodiazepine-2-one ,  1,5,6-Trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine-2-one ,  1,5-Dimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine ,  1,5,6-Trimethyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine

Terms in the title (3)： ベンゾジアゼピン類 ,  アトロプ異性 ,  立体配座