Art

J-GLOBAL ID：201402286929705222   Reference number：14A0164042

Remote induction of stereoselective 1,2-addition of aryl Grignard reagents to β-sulfinyl enones

アリールGrignard試薬のβ-スルフィニルエノンへの立体選択的1,2-付加の遠隔誘導

Author (5)： NAKAKITA Toshinori (School of Pharmacy, Nihon Univ., 7-7-1 Narashinodai, Funabashi-shi, Chiba 274-8555, JPN) ,  MIURA Motofumi (School of Pharmacy, Nihon Univ., 7-7-1 Narashinodai, Funabashi-shi, Chiba 274-8555, JPN) ,  TORIYAMA Masaharu (School of Pharmacy, Nihon Univ., 7-7-1 Narashinodai, Funabashi-shi, Chiba 274-8555, JPN) ,  MOTOHASHI Shigeyasu (School of Pharmacy, Nihon Univ., 7-7-1 Narashinodai, Funabashi-shi, Chiba 274-8555, JPN) ,  BARYBIN Mikhail V. (Dep. of Chemistry, The Univ. of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS 66045, USA)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 55  Issue： 5  Page： 1090-1092  Publication year： Jan. 29, 2014 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *Grignard reagent ,  asymmetric synthesis ,  addition reaction ,  *enone ,  sulfoxide ,  unsaturated alcohol ,  allyl compound ,  group(radical) ,  stereoselectivity
Semi thesaurus term： *1,2-addition ,  chiral auxiliary ,  diastereofacial selectivity

JST classification (2)： Group 1 and group 2 organic compounds  (CF09020Y) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (12)： [(R,Z)-3-Hydroxy-3-(3-methylphenyl)-2-methyl-1-heptenyl](4-methylphenyl) sulfoxide ,  [(R,Z)-3-Hydroxy-3-(4-chlorophenyl)-2-methyl-1-heptenyl](4-methylphenyl) sulfoxide ,  [(R,Z)-3-Hydroxy-3-(4-methylphenyl)-2-methyl-1-heptenyl](4-methylphenyl) sulfoxide ,  [(R,Z)-3-Hydroxy-3-(4-methoxyphenyl)-2-methyl-1-heptenyl](4-methylphenyl) sulfoxide ,  [(R,Z)-3-Hydroxy-3-phenyl-2-isopropyl-1-propenyl](4-methylphenyl) sulfoxide ,  [(R,Z)-3-Hydroxy-3-phenyl-2-butyl-1-propenyl](4-methylphenyl) sulfoxide ,  [(R,Z)-3-Hydroxy-3-phenyl-2-methyl-1-butenyl](4-methylphenyl) sulfoxide ,  [(R,Z)-3-Hydroxy-3-phenyl-2-methyl-1-heptenyl](4-methylphenyl) sulfoxide ,  [(Z)-3-Oxo-2-isopropyl-1-propenyl](4-methylphenyl) sulfoxide ,  [(Z)-3-Oxo-2-butyl-1-propenyl](4-methylphenyl) sulfoxide ,  [(Z)-3-Oxo-2-methyl-1-butenyl](4-methylphenyl) sulfoxide ,  [(Z)-3-Oxo-2-methyl-1-heptenyl](4-methylphenyl) sulfoxide

Terms in the title (3)： Grignard試薬 ,  立体 ,  誘導