Art

J-GLOBAL ID：201402291959608390   Reference number：14A0405077

Synthesis of Rh(I) Complexes Bearing N-p-Toluenesulfonyl-substituted N-Heterocyclic Carbenes

N-p-トルエンスルホニル置換N-複素環カルベンを有するRh(I)錯体の合成

Author (6)： SATO Tetsuo (Dep. of Applied Chemistry, Graduate School of Engineering, Tohoku Univ.) ,  SATO Tetsuo (Environment Conservation Res. Inst., Tohoku Univ.) ,  YOSHIOKA Daisuke (Dep. of Applied Chemistry, Graduate School of Engineering, Tohoku Univ.) ,  HIROSE Yoichi (Dep. of Applied Chemistry, Graduate School of Engineering, Tohoku Univ.) ,  OI Shuichi (Dep. of Applied Chemistry, Graduate School of Engineering, Tohoku Univ.) ,  OI Shuichi (Environment Conservation Res. Inst., Tohoku Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 43  Issue： 3  Page： 325-327 (J-STAGE)  Publication year： 2014 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： carbene ,  *nitrogen heterocyclic compound ,  *rhodium complex ,  sulfonate ,  substituent effect ,  crystal structure ,  infrared spectrum ,  *carbene complex
Semi thesaurus term： N-heterocyclic carbene

JST classification (3)： Crystal structure of complex of transition metals(excluding iron group)  (BK09030X) ,  Platinum family element complexes  (CE01100E) ,  Triazoles  (CF07084O)

Substance index (2)： (4-Methyl-2-tosyl-3,4-dihydro-2H-1,2,4-triazole-3-ylidene)radical ,  (1-Methyl-3-tosyl-2,3-dihydro-1H-imidazole-2-ylidene)radical

Reference (34)：

• 1) a) L. Benhamou, E. Chardon, G. Lavigne, S. Bellemin-Laponnaz, V. César, Chem. Rev. 2011, 111, 2705.
•  b) T. Dröge, F. Glorius, Angew. Chem., Int. Ed. 2010, 49, 6940.
•  c) F. E. Hahn, M. C. Jahnke, Angew. Chem., Int. Ed. 2008, 47, 3122.
•  d) M. Melaimi, M. Soleilhavoup, G. Bertrand, Angew. Chem., Int. Ed. 2010, 49, 8810.
•  e) P. de Frémont, N. Marion, S. P. Nolan, Coord. Chem. Rev. 2009, 253, 862.

Terms in the title (4)： 置換 ,  N-複素環カルベン ,  Rh ,  錯体