Art

J-GLOBAL ID：201502201630949887   Reference number：15A0328199

Organocatalytic Enantioselective Decarboxylative Reaction of Malonic Acid Half Thioesters with Cyclic N-Sulfonyl Ketimines by Using N-Heteroarenesulfonyl Cinchona Alkaloid Amides

N-ヘテロアレーンスルホニルキナアルカロイドアミドを使うマロン酸半チオエステルの環状N-スルホニルケチミンとの有機触媒的エナンチオ選択的脱カルボキシル反応

Author (5)： NAKAMURA Shuichi (Dep. of Frontier Materials, Graduate School of Engineering, Nagoya Inst. of Technol., Gokiso, Showa-ku, Nagoya ...) ,  SANO Masahide ,  TODA Ayaka ,  NAKANE Daisuke ,  MASUDA Hideki
Material： Chemistry - European Journal  (Chem Eur J)
Volume： 21  Issue： 10  Page： 3929-3932  Publication year： Mar. 02, 2015 
JST Material Number： W0744A  ISSN： 0947-6539  CODEN： CEUJED  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： asymmetric reaction ,  *decarboxylation reaction ,  asymmetric catalyst ,  quinoline alkaloid ,  sulfonamide ,  *thioester ,  sulfur heterocyclic compound ,  nitrogen heterocyclic compound ,  polynuclear aromatic compound ,  Mannich reaction ,  reaction mechanism ,  nucleophilic addition reaction ,  aliphatic carboxylic acid ,  dicarboxylic acid
Semi thesaurus term： Cinchona alkaloid

JST classification (3)： Thiazoles,isothiazoles  (CF07081P) ,  Aliphatic carboxylic acids,peroxycarboxylic acids,thiocarboxylic acids  (CF03200E) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (10)： Malonic acid ,  3-(Phenylthio)-3-oxopropanoic acid ,  3-(Ethoxycarbonyl)-1,2-benzoisothiazole 1,1-dioxide ,  (3R)-3β-(Ethoxycarbonyl)-3-[2-oxo-2-(phenylthio)ethyl]-2,3-dihydro-1,2-benzoisothiazole 1,1-dioxide ,  N-[(9R)-Cinchonan-9-yl]quinoline-8-sulfonamide ,  (3R)-3β-(Ethoxycarbonyl)-3-[2-oxo-2-(phenylthio)ethyl]-5-methoxy-2,3-dihydro-1,2-benzoisothiazole 1,1-dioxide ,  (3R)-3β-(Ethoxycarbonyl)-3-[2-oxo-2-(phenylthio)ethyl]-7-chloro-2,3-dihydro-1,2-benzoisothiazole 1,1-dioxide ,  (3S)-3α-(Ethoxycarbonyl)-3-[2-oxo-2-(phenylthio)ethyl]-7-chloro-2,3-dihydro-1,2-benzoisothiazole 1,1-dioxide ,  3-(Ethoxycarbonyl)naphtho[2,1-d]isothiazole 1,1-dioxide ,  (3S)-3α-(Ethoxycarbonyl)-3-[2-oxo-2-(phenylthio)ethyl]-2,3-dihydronaphtho[2,1-d]isothiazole 1,1-dioxide

Terms in the title (5)： マロン酸 ,  チオエステル ,  環状 ,  有機触媒 ,  脱カルボキシル反応