Art

J-GLOBAL ID：201502204558441857   Reference number：15A1328278

Boron Tribromide-Assisted Chiral Phosphoric Acid Catalyst for a Highly Enantioselective Diels-Alder Reaction of 1,2-Dihydropyridines

1,2-ジヒドロピリジン類の高エナンチオ選択的なDiels-Alder反応の三臭化ホウ素-支援キラルリン酸触媒

Author (5)： HATANO Manabu (Nagoya Univ., Nagoya, JPN) ,  GOTO Yuta (Nagoya Univ., Nagoya, JPN) ,  IZUMISEKI Atsuto (Nagoya Univ., Nagoya, JPN) ,  AKAKURA Matsujiro (Aichi Univ. Education, Kariya, JPN) ,  ISHIHARA Kazuaki (Nagoya Univ., Nagoya, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 137  Issue： 42  Page： 13472-13475  Publication year： Oct. 28, 2015 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,  chemical synthesis ,  *Diels-Alder reaction ,  boron bromide ,  *asymmetric catalyst ,  *bridged compound ,  Broensted acid ,  chemical compound ,  polynuclear aromatic compound ,  molecular structure ,  catalytic reaction ,  asymmetric reaction ,  density functional method ,  enantioselective synthesis ,  *Quinuclidines ,  asymmetric organocatalysis ,  binaphthalene derivative ,  Pyridines ,  chiral compound
Semi thesaurus term： DFT calculation ,  *chiral catalyst ,  binaphthyl derivative ,  Pyridines ,  chiral compound

JST classification (3)： Other condensed derivatives of pyridine  (CF07097Y) ,  Cyclization reaction,ring-opening reaction  (CF02050I) ,  Complexes of nonmetals  (CE01020R)

Substance index (15)： (2S,10aR)-2-Bromo-7-methoxy-1,2,3,9,10,10a-hexahydrophenanthrene-2-carbaldehyde ,  Dane diene ,  (1α,4α)-2-Chlorobicyclo[2.2.1]hepta-5-ene-2β-carbaldehyde ,  (1S,1β,4S,4β)-6-Methylnorborna-2-ene-6α-carbaldehyde ,  (1α,4α)-2-Bromobicyclo[2.2.1]hepta-5-ene-2β-carbaldehyde ,  (1β,4β)-2α-Chlorobicyclo[2.2.1]heptane-5-ene-2β-carbaldehyde ,  (1β,4β)-5-Methylnorborna-2-ene-5β-carbaldehyde ,  (1R,2R,4R)-2α-Bromo-2-formylnorborna-5-ene ,  (1β,4β)-2α-Chlorobicyclo[2.2.2]octane-5-ene-2β-carbaldehyde ,  (1α,4α)-2α-Chlorobicyclo[2.2.2]octane-5-ene-2-carbaldehyde ,  (1β,4β)-2β-Trifluoromethylbicyclo[2.2.1]heptane-5-ene-2α-carboxylic acid methyl ester ,  (1α,4α)-2β-Trifluoromethylbicyclo[2.2.1]heptane-5-ene-2α-carboxylic acid methyl ester ,  (1α,4α)-2α-Bromo-2β-formyl-7-azabicyclo[2.2.2]octane-5-ene-7-carboxylic acid phenyl ester ,  (1β,4β)-2α-Methyl-2β-formyl-7-azabicyclo[2.2.2]octane-5-ene-7-carboxylic acid phenyl ester ,  (1α,4α)-2α-Ethyl-2β-formyl-7-azabicyclo[2.2.2]octane-5-ene-7-carboxylic acid phenyl ester

Terms in the title (5)： ジヒドロピリジン類 ,  Diels-Alder反応 ,  三臭化ホウ素 ,  支援 ,  キラルリン酸触媒