Art

J-GLOBAL ID：201502205423599694   Reference number：15A1063574

Reversible Structural Changes Accompanying the Two-Electron Redox Reaction of Pt(tacn) (tacn: 1,4,7-triazacyclononane) Complexes

Pt(tacn)(tacn:1,4,7-トリアザシクロノナン)錯体の二電子酸化還元反応に伴う可逆的構造変化

Author (8)： WADA Tohru (Dep. of Chemistry, Coll. of Sci. and Res. Center of Smart Molecules, Rikkyo Univ.) ,  ENAMI Koki (Dep. of Chemistry, Coll. of Sci. and Res. Center of Smart Molecules, Rikkyo Univ.) ,  KOJIMA Ryohei (Dep. of Chemistry, Coll. of Sci. and Res. Center of Smart Molecules, Rikkyo Univ.) ,  OKADA Tomoki (Dep. of Chemistry, Coll. of Sci. and Res. Center of Smart Molecules, Rikkyo Univ.) ,  ISHIKAWA Yuki (Dep. of Chemistry, Coll. of Sci. and Res. Center of Smart Molecules, Rikkyo Univ.) ,  MIYAZATO Yuji (School of Sci. and Engineering, Tokyo Denki Univ.) ,  HORN Ernst (Dep. of Chemistry, Coll. of Sci. and Res. Center of Smart Molecules, Rikkyo Univ.) ,  MOCHIZUKI Yuji (Dep. of Chemistry, Coll. of Sci. and Res. Center of Smart Molecules, Rikkyo Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 88  Issue： 9  Page： 1230-1237 (J-STAGE)  Publication year： 2015 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *platinum complex ,  *nitrogen heterocyclic compound ,  *reduction(reaction) ,  *oxidation ,  *reversible change ,  *variation ,  chloro complex ,  perchlorate ,  complex formation ,  octahedron ,  X-ray diffraction ,  electrolyte ,  sodium chloride ,  aqueous solution ,  oxidation-reduction potential ,  anion ,  dissociation ,  association(chemical) ,  molecular orbital calculation ,  density functional method ,  proton magnetic resonance ,  Electrospray Ionization Mass Spectrometry ,  cyclic voltammetry ,  *crystal structure ,  molecular structure
Semi thesaurus term： Two Electron Reduction ,  two electron oxidation ,  *structural change ,  monocrystal X-ray diffraction ,  chloride ion ,  DFT calculation ,  ESI-MS ,  square wave voltammetry

JST classification (4)： Platinum family element complexes  (CE01100E) ,  Eight or more-membered heterocyclic compounds  (CF07120T) ,  Crystal structure of complex of transition metals(excluding iron group)  (BK09030X) ,  Electronic structure of molecules  (BH05010Q)

Substance index (2)： 1,4,7-Triazacyclononane ,  2,2'-Dipyridyl

Reference (41)：

• 1) F. R. Hartley, The Chemistry of Platinum and Palladium with Particular Reference to Complexes of the Elements, Applied Science Publishers, London, 1973.
• 2) E. M. Prokopchuk, R. J. Puddephatt, Can. J. Chem. 2003, 81, 476.
• 3) K. Wieghardt, M. Köppen, W. Swiridoff, J. Weiss, J. Chem. Soc., Dalton Trans. 1983, 1869.
• 4) V. V. Rostovtsev, L. M. Henling, J. A. Labinger, J. E. Bercaw, Inorg. Chem. 2002, 41, 3608.
• 5) H. Jude, J. A. K. Bauer, W. B. Connick, J. Am. Chem. Soc. 2003, 125, 3446.

Terms in the title (5)： Pt ,  錯体 ,  二電子酸化 ,  還元反応 ,  構造変化