Art

J-GLOBAL ID：201502205900700296   Reference number：15A0455648

Remote steric effects of C ₂-symmetric planar-chiral terpyridine ligands on copper-catalyzed asymmetric cyclopropanation reactions

銅触媒化不斉シクロプロパン化反応に対するC₂-対称面-キラルテルピリジンリガンドの遠隔立体効果

Author (5)： MUGISHIMA Nanako (Dep. of Chemistry and Biochemistry, Waseda Univ., 3-4-1 Ohkubo, Shinjuku-ku, Tokyo 169-8555, JPN) ,  KANOMATA Nobuhiro (Dep. of Chemistry and Biochemistry, Waseda Univ., 3-4-1 Ohkubo, Shinjuku-ku, Tokyo 169-8555, JPN) ,  KANOMATA Nobuhiro (Dep. of Applied Chemistry, Meiji Univ., 1-1-1 Higashimita, Tama-ku, Kawasaki 214-8571, JPN) ,  AKUTSU Norihiko (Dep. of Chemistry and Biochemistry, Waseda Univ., 3-4-1 Ohkubo, Shinjuku-ku, Tokyo 169-8555, JPN) ,  KUBOTA Hironobu (Dep. of Applied Chemistry, Meiji Univ., 1-1-1 Higashimita, Tama-ku, Kawasaki 214-8571, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 56  Issue： 14  Page： 1898-1903  Publication year： Apr. 01, 2015 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,  copper catalyst ,  *copper complex ,  asymmetric reaction ,  *cyclization reaction ,  chemical compound ,  ligand ,  steric effect ,  alkene ,  *chemical synthesis ,  *olefin compound ,  *aromatic compound ,  stereoselectivity ,  cyclophane ,  macrocyclic compound ,  proton magnetic resonance ,  13C NMR ,  mass spectrometry
Semi thesaurus term： 1H-NMR ,  C13NMR ,  HRMS(spectrometry) ,  *enantioselective synthesis ,  chiral compound ,  diastereoselection ,  *cyclopropanation ,  *Styrenes ,  *terpyridines ,  pyridinophane ,  ligand

JST classification (5)： Stereochemistry of organic reaction  (CF02130V) ,  Complexes of 9 and 10 groups  (CE01050Y) ,  Cyclization reaction,ring-opening reaction  (CF02050I) ,  Cyclopropanes  (CF04020P) ,  Catalytic reactions in general  (CB06080F)

Substance index (1)： Diazoacetic acid

Terms in the title (4)： 銅触媒 ,  シクロプロパン化 ,  C2 ,  立体効果