Art

J-GLOBAL ID：201502209621782971   Reference number：15A1239173

N-Heterocyclic carbene-catalyzed dimerization, cyclotetramerization and polymerization of Michael acceptors

Michael反応アクセプタのN-複素環カルベン触媒による二量化,環状四量化および重合

Author (1)： MATSUOKA Shin-ichi (Nagoya Inst. of Technol., Nagoya, JPN)
Material： Polymer Journal
Volume： 47  Issue： 11  Page： 713-718  Publication year： Nov. 2015 
JST Material Number： F0612A  ISSN： 0032-3896  CODEN： POLJB8  Document type： Article
Article type： 解説  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *Michael reaction ,  *carbene ,  *nitrogen heterocyclic compound ,  dimerization ,  cyclization reaction ,  consecutive reaction ,  reaction mechanism ,  nucleophilic reaction ,  C-O bond ,  carbonyl compound ,  carbonyl group ,  aldehyde ,  Lewis base ,  base catalytic reaction ,  carbene complex ,  polymerization catalyst ,  polymerization initiator ,  P4VP ,  polymethyl methacrylate ,  proton shift ,  *acceptor ,  nucleophilic reagent ,  transition metal complex ,  reaction intermediate ,  radical polymerization ,  unsaturated fatty acid ,  olefin compound ,  carboxylate(ester) ,  vinyl compound ,  aliphatic nitrile ,  aliphatic carboxylic acid ,  unsaturated carboxylic acid ,  aliphatic aldehyde ,  unsaturated aldehyde
Semi thesaurus term： *N-heterocyclic carbene ,  PMMA ,  poly-4-vinylpyridine ,  addition polymerization

JST classification (3)： Polymerization catalyst,polymerization initiator  (CG04070V) ,  Polymerization in general  (CG04010H) ,  Catalytic reactions in general  (CB06080F)

Substance index (16)： 2-Vinylpyridine ,  4-Vinylpyridine ,  Acrylic acid butyl ,  Acrylic acid tert-butyl ,  Acrylic acid methyl ,  Acrylonitrile ,  N,N-Dimethylacrylamide ,  Methacrylic acid 2-(dimethylamino)ethyl ,  Methacrylic acid tert-butyl ,  Methacrylic acid butyl ,  Methacrylic acid methyl ,  Methacrolein ,  (1,3,4-Triphenyl-1H-1,2,4-triazole-5-ylidene)radical ,  1,3,4-Triphenyl-5-methoxy-4,5-dihydro-1H-1,2,4-triazole ,  Ethene-1,2-diylbis(mesitylimino)carbene ,  1,2-Ethenediylbis(2,6-diisopropylphenylimino)carbene

Reference (53)：

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Terms in the title (8)： Michael反応 ,  アクセプタ ,  N-複素環カルベン ,  触媒 ,  二量化 ,  環状 ,  四量化 ,  重合