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J-GLOBAL ID：201502217088389564   Reference number：15A1289240

Unprecedented Formation of 2-Aryl-3-oxocyclobut-1-enyl Ligand from 3-Arylpropargyl Chloride, Carbon Monoxide, and Pd(0) or Pt(0) Complex

3-アリールプロパルギルクロリド,一酸化炭素,及びPd(0)又はPt(0)錯体からの2-アリール-3-オキソシクロブテ-1-ニル配位子の初めての生成

Author (5)： AZAMI Hidekazu (Dep. of Applied Chemistry, Graduate School of Engineering, Saitama Inst. of Technol.) ,  TSUKADA Takuro (Dep. of Life Sci. and Green Chemistry, Fac. of Engineering, Saitama Inst. of Technol.) ,  TANIFUJI Ryutaro (Dep. of Applied Chemistry, Graduate School of Engineering, Saitama Inst. of Technol.) ,  SEKI Ryosuke (Dep. of Applied Chemistry, Graduate School of Engineering, Saitama Inst. of Technol.) ,  IWASAKI Masakazu (Dep. of Applied Chemistry, Graduate School of Engineering, Saitama Inst. of Technol.)
Material： Chemistry Letters  (Chem Lett)
Volume： 44  Issue： 11  Page： 1550-1551 (J-STAGE)  Publication year： 2015 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *aromatic chlorine compound ,  *phenol ether ,  *acetylenic compound ,  *aliphatic chlorine compound ,  *cycloalkene ,  *ketone ,  *carbon monoxide ,  *palladium complex ,  *platinum complex ,  organophosphorus compound ,  complex formation ,  crystal structure ,  molecular structure ,  organopalladium compound ,  organoplatinum compound ,  cyclization reaction ,  X-ray diffraction ,  proton magnetic resonance ,  aromatic compound

JST classification (4)： Cyclobutanes  (CF04030A) ,  Platinum family element complexes  (CE01100E) ,  Organop phosphorus compounds  (CF08040N) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (7)： Triphenylphosphine ,  1-(4-Chlorophenyl)-3-chloro-1-propyne ,  1-(4-Methylphenyl)-3-chloro-1-propyne ,  1-(4-Methoxyphenyl)-3-chloro-1-propyne ,  2-[3-(4-Chlorophenyl)-2-propynyl]-1-cyclobutene-3-one ,  2-[3-(4-Methylphenyl)-2-propynyl]-1-cyclobutene-3-one ,  2-[3-(4-Methoxyphenyl)-2-propynyl]-1-cyclobutene-3-one

Reference (21)：

• 1) a) J. Tsuji, T. Nogi, Tetrahedron Lett. 1966, 7, 1801.
•  b) T. Nogi, J. Tsuji, Tetrahedron 1969, 25, 4099.
•  c) J. Tsuji, J. Organomet. Chem. 1986, 300, 281.
•  d) J. Tsuji, T. Mandai, J. Organomet. Chem. 1993, 451, 15.
•  e) J. Tsuji, T. Mandai, Angew. Chem., Int. Ed. Engl. 1996, 34, 2589.

Terms in the title (5)： 一酸化炭素 ,  Pd ,  Pt ,  錯体 ,  配位子