Art

J-GLOBAL ID：201502267519077472   Reference number：15A0336640

Diastereo- and enantioselective intramolecular 1,6-C-H insertion reactions of α-diazo esters catalyzed by chiral dirhodium(II) carboxylates

キラルジロジウム(II)カルボン酸エステル触媒によるα-ジアゾエステルのジアステレオおよびエナンチオ選択的分子内1,6-C-H挿入反応

Author (6)： ITO Motoki (Fac. of Pharmaceutical Sciences, Hokkaido Univ., Sapporo 060-0812, JPN) ,  KONDO Yuji (Fac. of Pharmaceutical Sciences, Hokkaido Univ., Sapporo 060-0812, JPN) ,  NAMBU Hisanori (Fac. of Pharmaceutical Sciences, Hokkaido Univ., Sapporo 060-0812, JPN) ,  ANADA Masahiro (Fac. of Pharmaceutical Sciences, Hokkaido Univ., Sapporo 060-0812, JPN) ,  TAKEDA Koji (Fac. of Pharmaceutical Sciences, Hokkaido Univ., Sapporo 060-0812, JPN) ,  HASHIMOTO Shunichi (Fac. of Pharmaceutical Sciences, Hokkaido Univ., Sapporo 060-0812, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 56  Issue： 11  Page： 1397-1400  Publication year： Mar. 11, 2015 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  catalytic reaction ,  rhodium catalyst ,  rhodium complex ,  *insertion reaction ,  *diazo compound ,  *carboxylate(ester) ,  ether ,  oxygen heterocyclic compound ,  ylide ,  rearrangement reaction ,  hydride shift
Semi thesaurus term： tetrahydropyran derivative

JST classification (2)： Pyranes  (CF07092R) ,  Catalytic reactions in general  (CB06080F)

Substance index (9)： N,N-Phthaloyl-3-methylvaline ,  2β-[(E)-1-Propenyl]tetrahydro-2H-pyran-3β-carboxylic acid methyl ester ,  2β-Ethyltetrahydro-2H-pyran-3β-carboxylic acid methyl ester ,  2β-Vinyltetrahydro-2H-pyran-3β-carboxylic acid tert-butyl ester ,  2β-Vinyltetrahydro-2H-pyran-3β-carboxylic acid methyl ester ,  2-Diazo-5-(allyloxy)valeric acid methyl ester ,  2-Diazo-5-[[(E)-2-butenyl]oxy]valeric acid methyl ester ,  3β-Vinyl-3,4-dihydro-1H-2-benzopyran-4β-carboxylic acid methyl ester ,  α-Diazo-2-(allyloxymethyl)benzeneacetic acid methyl ester

Terms in the title (3)： カルボン酸エステル ,  触媒 ,  挿入反応