Art

J-GLOBAL ID：201502286590076708   Reference number：15A0170097

1,3,5-[(^tBu₂MeSi)₂Si]₃C₆H₃: Isolable Si-centered Triradical with a High-spin Quartet Ground State

1,3,5-[(^tBu₂MeSi)₂Si]₃C₆H₃ 高スピン四重項状態の単離可能なSi中心トリラジカル

Author (3)： NOZAWA Takeshi (Dep. of Chemistry, Graduate School of Pure and Applied Sciences, Univ. of Tsukuba) ,  ICHINOHE Masaaki (Dep. of Chemistry, Graduate School of Pure and Applied Sciences, Univ. of Tsukuba) ,  SEKIGUCHI Akira (Dep. of Chemistry, Graduate School of Pure and Applied Sciences, Univ. of Tsukuba)
Material： Chemistry Letters  (Chem Lett)
Volume： 44  Issue： 1  Page： 56-57 (J-STAGE)  Publication year： 2015 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *organosilicon compound ,  *radical ,  *aromatic compound ,  *high-spin state ,  *quartet ,  *isolation (separation) ,  chemical synthesis ,  intercalation compound ,  Potassium ,  Graphite ,  X-Ray Diffraction ,  crystal structure ,  spectrum ,  ESR ,  *ground state ,  Curie-Weiss law ,  reactivity ,  graphite intercalation compound ,  *energy level ,  *excited state
Semi thesaurus term： EPR ,  graphite intercalation compound ,  electron paramagnetic resonance ,  electron paramagnetic resonance spectrum

JST classification (2)： Organosilicon compounds  (CF08030C) ,  Crystal structure of organometalloidal and organometallic compounds  (BK08040B)

Substance index (2)： 2,2′,2′′-(1,3,5-Benzenetriyl)tris(1,1,3,3-tetra-tert-butyl-1,3-dimethyl-2-iodotrisilane) ,  [(Benzene-1,3,5-triyl)tris[bis(methyldi-tert-butylsilyl)silylene]]radical

Reference (27)：

• 1) Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds, ed. by R. G. Hicks, Wiley, Chichester, 2010. doi:10.1002/9780470666975.
• 2) a) C. Chatgilialoglu, Chem. Rev. 1995, 95, 1229.
•  b) C. Chatgilialoglu, C. H. Schiesser, in The Chemistry of Organic Silicon Compounds, ed. by Z. Rappoport, Y. Apeloig, Wiley, Chichester, 2001, Vol. 3, Chap. 4. doi:10.1002/0470857269.ch4.
•  c) M. W. Carland, C. H. Schiesser, in The Chemistry of Organic Germanium, Tin and Lead Compounds, Z. Rappoport, Wiley, Chichester, 2002, Vol. 2, Part 2, Chap. 19. doi:10.1002/0470857188.ch19.
• 3) M. M. Olmstead, L. Pu, R. S. Simons, P. P. Power, Chem. Commun. 1997, 1595.

Terms in the title (4)： 単離 ,  Si ,  トリ ,  ラジカル