Art

J-GLOBAL ID：201502290320716338   Reference number：15A0261322

Functionalized aryl-β-C-glycoside synthesis by Barbier-type reaction using 2,4,6-triisopropylphenyllithium

2,4,6-トリイソプロピルフェニルリチウムを使用したBarbier型反応による官能化アリール-β-C-グリコシドの合成

Author (5)： OHBA Kiyomi (Medicinal Chemistry Res. Laboratories, Mitsubishi Tanabe Pharma Corp., 1000 Kamoshida-cho, Aoba-ku, Yokohama ...) ,  OHBA Kiyomi (Dep. of Applied Chemistry, Fac. of Sci. and Technol., Keio Univ., 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, JPN) ,  KOGA Yuichi (Medicinal Chemistry Res. Laboratories, Mitsubishi Tanabe Pharma Corp., 1000 Kamoshida-cho, Aoba-ku, Yokohama ...) ,  NOMURA Sumihiro (Medicinal Chemistry Res. Laboratories, Mitsubishi Tanabe Pharma Corp., 1000 Kamoshida-cho, Aoba-ku, Yokohama ...) ,  NAKATA Masaya (Dep. of Applied Chemistry, Fac. of Sci. and Technol., Keio Univ., 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 56  Issue： 8  Page： 1007-1010  Publication year： Feb. 18, 2015 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,  *addition reaction ,  *exchange reaction ,  deoxygenation ,  aldonic acid ,  lactone ,  *glycoside ,  aromatic halogen compound ,  organolithium compound ,  carboxylate (ester) ,  nitrile ,  carbonyl compound ,  *C-glucoside ,  *Barbier reaction ,  carbohydrate
Semi thesaurus term： *Barbier type reaction

JST classification (1)： Monosaccharides  (CF10052H)

Substance index (16)： 1-(2-Carboxyphenyl)-1-deoxy-β-D-glucopyranose 1,2-lactone ,  1-(2-Carboxyphenyl)-D-glucopyranose 1,1-lactone ,  2,3-Bis(benzyloxy)-5-(2-O,3-O,4-O,6-O-tetrabenzyl-α-D-glucopyranose-1-yl)benzoic acid methyl ester ,  2,3-Bis(benzyloxy)-5-(2-O,3-O,4-O,6-O-tetrabenzyl-β-D-glucopyranosyl)benzoic acid methyl ester ,  2-O,3-O,4-O,6-O-Tetrabenzyl-D-gluconic acid lactone ,  4-(1-O-Methyl-α-D-glucopyranose-1-yl)benzoic acid isopropyl ester ,  4-(2-O,3-O,4-O,6-O-Tetrabenzyl-α-D-glucopyranose-1-yl)benzonitrile ,  4-(2-O,3-O,4-O,6-O-Tetrabenzyl-α-D-glucopyranose-1-yl)benzoic acid tert-butyl ester ,  4-(2-O,3-O,4-O,6-O-Tetrabenzyl-α-D-mannopyranose-1-yl)benzoic acid tert-butyl ester ,  4-(2-O,3-O,4-O,6-O-Tetrabenzyl-β-D-glucopyranosyl)benzonitrile ,  4-(2-O,3-O,4-O,6-O-Tetrabenzyl-β-D-glucopyranosyl)benzoic acid ,  4-(2-O,3-O,4-O,6-O-Tetrabenzyl-β-D-mannopyranosyl)benzoic acid ,  4-(2-O,3-O,5-O-Tribenzyl-D-ribofuranose-1-yl)benzoic acid tert-butyl ester ,  4-(2-O,3-O,5-O-Tribenzyl-β-D-ribofuranosyl)benzoic acid ,  4-β-D-Glucopyranosylbenzoic acid isopropyl ester ,  tert-Butyl 4-iodobenzoate

Terms in the title (3)： Barbier型反応 ,  官能化 ,  C-グリコシド