Rchr
J-GLOBAL ID:201601004360771520
Update date: Sep. 03, 2024
Shirai Tomohiko
シライ トモヒコ | Shirai Tomohiko
Affiliation and department:
Research field (1):
Synthetic organic chemistry
Research keywords (2):
不斉合成
, 有機金属化学
Research theme for competitive and other funds (12):
- 2024 - 2027 超疎水化多孔性錯体結晶を駆使した水中有機フッ素化合物処理技術の開拓
- 2023 - 2024 芳香族カルボン酸の触媒的脱炭酸を伴う不斉炭素-炭素結合形成反応
- 2023 - 2024 天然物をモデル化合物とした新規機能性成分の創造
- 2023 - 2024 分子に潜在する温室効果ガスの触媒的抽出/再固定化を利用した光学活性化合物合成法
- 2022 - 2023 炭素-炭素結合切断を基軸とする機能性有機材料の新規合成法
- 2022 - 2023 芳香族カルボン酸の触媒的脱炭酸を伴う不斉炭素-炭素結合形成反応
- 2022 - 2023 一酸化炭素及び二酸化炭素の新しい触媒的固定化技術の創出
- 2019 - 2023 アルデヒドの炭素-炭素結合切断を伴うアルケンの不斉カルボホルミル化反応
- 2021 - 2022 芳香族カルボン酸の触媒的脱炭酸を伴う不斉炭素-炭素結合形成反応
- 2018 - 2019 求核性の制御に基づくC-H不斉官能基化反応
- 2016 - 2018 C-H結合不斉官能基化反応を指向したキラル触媒の開発
- 2014 - 2016 C-H結合活性化を経る、C=O、C=N結合への不斉付加反応の開発
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Papers (17):
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T. Shirai, T. Yamasaki. Tandem Decarboxylation/Fluorination of N-Acetylanthranilic Acids by Iridium Complexes. Journal of Fluorine Chemistry. 2024
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R. Nonami, Y. Kishino, T. Yamasaki, K. Kanemoto, K. Iwai, N. Nishiwaki, K. Shibatomi, T. Shirai. Cationic Iridium-Catalyzed Decarboxylation of Aromatic Carboxylic Acids. Chemistry - An Asian Journal. 2023
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R. Nonami, Y. Morimoto, K. Kanemoto, Y. Yamamoto, T. Shirai. Cationic Iridium-Catalyzed Asymmetric Decarbonylative Aryl Addition of Aromatic Aldehydes to Bicyclic Alkenes. Chemistry - A European Journal. 2022. 28. 10
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T. Shirai, Y. Yamamoto. Cationic Iridium/Chiral Bidentate Phosphoramidite Catalyzed Asymmetric Hydroarylation. Synthesis. 2021
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H. Fujita, H. Yoshimatsu, C. Miki, T. Shirai, T. Hata, M. Sakamoto. Acceleration of Mukaiyama Epoxidation Using O2 Fine Bubbles. Chemistry Letters. 2021. 50. 5. 1066-1070
more...
MISC (5):
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R. Nonami, Y. Kishino, T. Yamasaki, K. Kanemoto, K. Iwai, N. Nishiwaki, K. Shibatomi, T. Shirai. Front Cover: Cationic Iridium-Catalyzed Decarboxylation of Aromatic Carboxylic Acids (Chem. Asian J. 17/2023). Chemistry - An Asian Journal. 2023. 17
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Reina Nonami, Yusei Morimoto, Kazuya Kanemoto, Yasunori Yamamoto, Tomohiko Shirai. Cover Profile: Cationic Iridium-Catalyzed Asymmetric Decarbonylative Aryl Addition of Aromatic Aldehydes to Bicyclic Alkenes. Chemistry - A European Journal. 2022. 28. 10
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Reina Nonami, Yusei Morimoto, Kazuya Kanemoto, Yasunori Yamamoto, Tomohiko Shirai. Front Cover: Cationic Iridium-Catalyzed Asymmetric Decarbonylative Aryl Addition of Aromatic Aldehydes to Bicyclic Alkenes (Chem. Eur. J. 10/2022). Chemistry - A European Journal. 2022. 28. 10
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Tomohiko Shirai, Takakazu Okamoto, Yasunori Yamamoto. Front Cover: Iridium-Catalyzed Direct Asymmetric Alkylation of Aniline Derivatives using 2-Norbornene (Asian J. Org. Chem. 6/2018). Asian Journal of Organic Chemistry. 2018. 7. 6. 984-984
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Tomohiko Shirai, Hajime Ito, Yasunori Yamamoto. Back Cover: Cationic Ir/Me-BIPAM-Catalyzed Asymmetric Intramolecular Direct Hydroarylation of α-Ketoamides (Angew. Chem. Int. Ed. 10/2014). Angewandte Chemie International Edition. 2014. 53. 10. 2778-2778
Lectures and oral presentations (46):
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Reversible Chirality Inversion of m-Quaterphenyl-Aminoindanol Conjugates by Temperature Change
(34th International Symposium on Chirality 2024)
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Synthesis of Oxindole-Type Chiral Derivatizing Agents and Determination of the Absolute Configuration of Chiral Primary Amines
(34th International Symposium on Chirality 2024)
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Cationic Iridium-Catalyzed Asymmetric Hydroarylation of Bicyclic Alkenes via C-C Activation
(34th International Symposium on Chirality 2024)
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カチオン性イリジウム触媒を用いる芳香族カルボン酸の脱炭酸反応とフッ素化への応用
(2023ハロゲン利用ミニシンポジウム 2023)
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芳香族カルボン酸の触媒的脱炭酸を伴う不斉炭素-炭素結合形成反応
(2022年度先進的技術シンポジウム 2023)
more...
Education (4):
- 2013 - 2016 Hokkaido University Graduate School of Chemical Sciences and Engineering Division of Chemical Sciences and Engineering
- 2009 - 2011 Hokkaido University Graduate School of Engineering Division of Chemical Process Engineering
- 2007 - 2009 Hokkaido University School of Engineering Department of Applied Science and Engineering
- 2002 - 2007 Ibaraki National College of Technology
Professional career (1):
Work history (8):
- 2024/04 - 現在 Toho University
- 2022/04 - 2024/03 高知工業高等専門学校ソーシャルデザイン工学科 准教授
- 2020/12 - 2024/03 Kochi University of Technology, visiting researcher
- 2021/07 - 2022/03 高知工業高等専門学校ソーシャルデザイン工学科 講師
- 2016/04 - 2021/06 National Institute of Technology, Kochi College Department of Social Design Engineering
- 2020/03 - 2020/08 University of Toronto
- 2014/04 - 2016/03 日本学術振興会特別研究員(DC2)
- 2011/04 - 2012/12 日立化成工業株式会社 開発職
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Committee career (1):
- 2021/11 - 2021年日本化学会中国四国支部大会 高知大会 実行委員
Awards (5):
- 2022/03 - 高知工業高等専門学校教職員表彰(研究・学生指導)
- 2015/01 - Molecules Best Paper Award 2015 (3rd Prize)
- 2014/07 - 万有札幌シンポジウム ベストポスター賞
- 2014/06 - The 3rd Frontier Chemistry Center International Symposium Poster Award
- 2011/03 - 北海道大学大学院工学研究科 大塚博先生記念賞
Association Membership(s) (2):
THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY, JAPAN
, THE CHEMICAL SOCIETY OF JAPAN
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