Art

J-GLOBAL ID：201602202392544827   Reference number：16A0145637

Relationship between the Bowl-Shaped Geometry of Phosphangulene and an Axial Group on the Phosphorus Atom

ホスファングレンのボウル型幾何形状とリン原子上の軸基との関係

Author (2)： YAMAMURA Masaki (Graduate School of Pure and Applied Sciences and Tsukuba Res. Center for Interdisciplinary Materials Sci. (TIMS) ...) ,  NABESHIMA Tatsuya (Graduate School of Pure and Applied Sciences and Tsukuba Res. Center for Interdisciplinary Materials Sci. (TIMS) ...)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 89  Issue： 1  Page： 42-49 (J-STAGE)  Publication year： 2016 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *morphology(form) ,  *ligand ,  molecular orbital method ,  density functional method ,  NMR ,  infrared radiation ,  lone pair ,  *phosphorus heterocyclic compound ,  *heterocyclic compound ,  *oxygen heterocyclic compound ,  cyclic voltammetry ,  bond angle
Semi thesaurus term： *geometric architecture ,  *Heterocyclic Compounds with 4 or More Rings ,  NBO analysis ,  *axial ligand

JST classification (2)： Other 6-membered rings with two hetero atoms  (CF07106V) ,  Complexes of nonmetals  (CE01020R)

Substance index (1)： Phosphangulene

Reference (26)：

• 1) a) N. G. Andersen, B. A. Keay, Chem. Rev. 2001, 101, 997.
•  b) A. F. Littke, G. C. Fu, Angew. Chem., Int. Ed. 2002, 41, 4176.
• 2) a) F. C. Krebs, P. S. Larsen, J. Larsen, C. S. Jacobsen, C. Boutton, N. Thorup, J. Am. Chem. Soc. 1997, 119, 1208.
•  b) G. K. H. Madsen, F. C. Krebs, B. Lebech, F. K. Larsen, Chem.—Eur. J. 2000, 6, 1797.
• 3) a) M. Yamamura, T. Saito, T. Nabeshima, J. Am. Chem. Soc. 2014, 136, 14299.

Terms in the title (3)： ボウル ,  幾何形状 ,  リン原子