Art

J-GLOBAL ID：201602206894461440   Reference number：16A0145382

Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary Stereocenters

第四立体中心を構築する三置換アルケン類のインドール類によるエナンチオ選択的な脱水素Heckアリール化

Author (4)： ZHANG Chun (Univ. Utah, Utah, USA) ,  SANTIAGO Celine B. (Univ. Utah, Utah, USA) ,  CRAWFORD Jennifer M. (Univ. Utah, Utah, USA) ,  SIGMAN Matthew S. (Univ. Utah, Utah, USA)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 137  Issue： 50  Page： 15668-15671  Publication year： Dec. 23, 2015 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,  *polynuclear aromatic compound ,  unsaturated alcohol ,  dehydrogenation(chemical reaction) ,  *Heck reaction ,  arylation ,  asymmetric reaction ,  palladium catalyst ,  chiral ligand ,  *ligand effect ,  atom ,  stereochemistry
Semi thesaurus term： *indoles ,  stereogenic center

JST classification (2)： Condensed derivatives of pyrroles  (CF07077C) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (15)： (E)-3-Ethyl-2-heptene-1-ol ,  (S)-3-Ethyl-3-(1-methyl-1H-indole-3-yl)-1-heptanone ,  (S)-3-Ethyl-3-(1-methyl-1H-indole-3-yl)-5-phenyl-1-pentanone ,  (R)-3-Cyclopentyl-3-(1-methyl-1H-indole-3-yl)-1-pentanone ,  (S)-3-Cyclohexylmethyl-3-(1-methyl-1H-indole-3-yl)-1-pentanone ,  (R)-2-(5-Trifluoromethyl-2-pyridyl)-4-(2-naphthylmethyl)-4,5-dihydrooxazole ,  (S)-3-Methyl-3-(1-methyl-1H-indole-3-yl)-1-heptanone ,  (S)-3-Methyl-3-(1-methyl-1H-indole-3-yl)-5-phenyl-1-pentanone ,  (S)-3-Methyl-3-(1-methyl-1H-indole-3-yl)-6-methyl-1-heptanone ,  (R)-4-Methyl-4-(1-methyl-1H-indole-3-yl)-1-hexanone ,  (S)-3-Ethyl-3-(1-methyl-5-fluoro-1H-indole-3-yl)-1-heptanone ,  (S)-3-Ethyl-3-(1-benzyl-1H-indole-3-yl)-1-heptanone ,  (S)-3-Methyl-3-(1-isopropyl-1H-indole-3-yl)-1-heptanone ,  (S)-3-Ethyl-3-(1-isopropyl-1H-indole-3-yl)-1-heptanone ,  (R)-2-(3-Fluoro-2-pyridyl)-4-(2-naphthylmethyl)-4,5-dihydrooxazole

Terms in the title (7)： 立体中心 ,  構築 ,  置換 ,  アルケン ,  インドール類 ,  脱水素 ,  アリール化