Art

J-GLOBAL ID：201602217562761724   Reference number：16A0710842

Solvent effect for the oxidation of cyclohexene with an active oxygen species produced by reducing dioxygen

酸素分子の還元活性化により発生させた活性酸素種によるシクロヘキセンの酸化に対する溶媒効果

Author (2)： TSUDA YOSHIHIRO (福井工高専) ,  HIRONO HIDEAKI (福井工高専)
Material： 技術・教育研究論文誌  (Journal of Technology and Education)
Volume： 23  Issue： 1  Page： 1-6  Publication year： Jun. 30, 2016 
JST Material Number： L2883A  ISSN： 1342-6079  CODEN： DKGRFL  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： JAPANESE (JA)

Thesaurus term： *Oxygen ,  *diatomic molecule ,  *reduction (reaction) ,  *activation ,  *active oxygen ,  *cycloalkene ,  *oxidation ,  *solvent effect ,  reducing agent ,  metal powder ,  additive ,  anion ,  nonpolar solvent ,  solvent ,  reaction mechanism ,  reaction product ,  permittivity ,  basicity (property) ,  electronic structure ,  polar solvent ,  *dioxygen ,  zinc powder ,  activating agent ,  bromide ion ,  electron pair ,  aromatic carboxylic acid ,  aliphatic chlorine compound ,  aliphatic nitrile
Semi thesaurus term： *Reactive Oxygen Species ,  non-polar solvent ,  relative permittivity

JST classification (3)： Oxidation,reduction  (CF02060T) ,  Catalytic reactions(homogeneous system)  (CB06090Q) ,  Cyclohexanes  (CF04050W)

Substance index (8)： Cyclohexene ,  Hexylviologen ,  Benzoic acid anhydride ,  Methylene chloride ,  Acetonitrile ,  Cyclohexene oxide ,  2-Cyclohexen-1-one ,  2-Cyclohexen-1-ol

Reference (10)：

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• Y. Suzuki, Y. Koseki, K. Takahashi, S. Matsui and T. Komura, Electrocatalytic epoxidation of cyclohexene by Manganese (III)porphyrin using electron mediator, Bull. Chem. Soc. Jpn., 67, 847-854 (1994).
• I. Yamanaka, K. Nakagaki, T. Akimoto and K. Otsuka, Reactivity of active oxygen species generated in the EuCl₃ catalytic system for monooxygenation of hydrocarbons, J. Chem. Soc., Perkin Trans. 2, 2511-2517 (1996).

Terms in the title (7)： 酸素分子 ,  還元 ,  活性化 ,  活性酸素種 ,  シクロヘキセン ,  酸化 ,  溶媒効果