Art

J-GLOBAL ID：201602218773320578   Reference number：16A0918385

Aryl radical cyclization with alkyne followed by tandem carboxylation in methyl 4-tert-butylbenzoate-mediated electrochemical reduction of 2-(2-propynyloxy)bromobenzenes in the presence of carbon dioxide

2-(2-プロピニルオキシ)ブロモベンゼン類の,アルキンとのアリールラジカル環化,つづく二酸化炭素の存在下,4-tert-ブチル安息香酸メチル媒介電気化学的還元によるタンデムカルボキシル化

Author (5)： Katayama Asahi (Laboratory of Organic Reaction, Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan) ,  Senboku Hisanori (Laboratory of Organic Reaction, Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan) ,  Senboku Hisanori (Laboratory of Organic Reaction, Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan) ,  Hara Shoji (Laboratory of Organic Reaction, Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan) ,  Hara Shoji (Laboratory of Organic Reaction, Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 72  Issue： 31  Page： 4626-4636  Publication year： Aug. 04, 2016 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,  electrolytic synthesis ,  aryl radical ,  *radical reaction ,  *cyclization reaction ,  carbon dioxide ,  consecutive reaction ,  aromatic bromine compound ,  acetylenic compound ,  oxygen heterocyclic compound ,  polynuclear aromatic compound ,  nitrogen heterocyclic compound ,  sulfur heterocyclic compound ,  alicyclic compound ,  *dicarboxylic acid ,  reaction mechanism ,  *carboxylation
Semi thesaurus term： *carboxylation ,  Indans ,  indoline derivatives ,  tandem reaction ,  *free-radical cyclization ,  Benzothiophene derivatives ,  Benzopyrans ,  Benzofurans ,  electrochemical synthesis

Author keywords (5)： Electrochemical carboxylation ,  Aryl radical ,  Radical cyclization ,  Fixation of carbon dioxide ,  Tandem reaction

JST classification (1)： Aromatic monocyclic halogen compounds  (CF05030H)

Substance index (15)： 1-Carboxyindan-1-acetic acid ,  4-(2-Bromophenyl)-1-butyne ,  2-Methyl-3-carboxy-2,3-dihydrobenzofuran-3-acetic acid ,  3-(Carboxymethyl)indoline-1,3-dicarboxylic acid 1-tert-butyl ester ,  3-(Methoxycarbonyl)-2,3-dihydrobenzofuran-3-acetic acid methyl ester ,  3-[(5β)-3-Oxabicyclo[3.1.0]hexane1β-yl]indoline-1,3-dicarboxylic acid 1-tert-butyl ester ,  3-[(5β)-3-Oxabicyclo[3.1.0]hexane1β-yl]-2,3-dihydrobenzofuran-3-carboxylic acid ,  3-Carboxy-2,3-dihydrobenzo[b]thiophene-3-acetic acid ,  2,3-Dihydro-3-carboxybenzofuran-3-acetic acid ,  4-(Allyloxy)-2-butynyl(2-bromophenyl) ether ,  4-Carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid ,  Propargyl(2-bromophenyl)carbamic acid tert-butyl ester ,  Spiro[benzofuran-3(2H),3′(2′H)-furan]-5′(4′H)-one ,  2-Bromophenylpropargyl ether ,  Propargyl(2-bromophenyl) sulfide

Terms in the title (9)： ブロモベンゼン類 ,  アルキン ,  アリールラジカル ,  環化 ,  二酸化炭素 ,  4-tert-ブチル安息香酸メチル ,  電気化学的還元 ,  タンデム ,  カルボキシル化