Art

J-GLOBAL ID：201602245996964682   Reference number：16A0837715

Efficient acylation and transesterification catalyzed by dilithium tetra-tert-butylzincate at low temperatures

低温でのジリチウムテトラ-tert-ブチルジンケートが触媒する効率的アシル化およびエステル交換反応

Author (5)： Oshimura Miyuki (Department of Chemical Science and Technology, Institute of Technology and Science, Tokushima University, 2-1 Minami-josanjima, Tokushima 770-8506, Japan) ,  Oda Yuki (Department of Chemical Science and Technology, Institute of Technology and Science, Tokushima University, 2-1 Minami-josanjima, Tokushima 770-8506, Japan) ,  Kondoh Keita (Department of Chemical Science and Technology, Institute of Technology and Science, Tokushima University, 2-1 Minami-josanjima, Tokushima 770-8506, Japan) ,  Hirano Tomohiro (Department of Chemical Science and Technology, Institute of Technology and Science, Tokushima University, 2-1 Minami-josanjima, Tokushima 770-8506, Japan) ,  Ute Koichi (Department of Chemical Science and Technology, Institute of Technology and Science, Tokushima University, 2-1 Minami-josanjima, Tokushima 770-8506, Japan)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 57  Issue： 19  Page： 2070-2073  Publication year： May. 11, 2016 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： zinc complex ,  *zinc compound ,  *transition metal catalyst ,  *Acylation ,  *ester interchange ,  molecular sieve ,  proton magnetic resonance ,  *zinc catalyst ,  fatty acid ,  aliphatic alcohol ,  enol ester ,  vinyl compound ,  unsaturated alcohol
Semi thesaurus term： *interesterification ,  *acylation ,  molecular sieves ,  1H-NMR

Author keywords (4)： Acylation ,  Transesterification ,  Zinc catalyst ,  Chemoselectivity

JST classification (4)： Substitution reaction  (CF02020B) ,  Catalytic reactions(homogeneous system)  (CB06090Q) ,  Other catalysts  (CB06123Z) ,  Organo metallic compounds in general  (CF09010N)

Substance index (1)： Acetic acid vinyl ester

Terms in the title (5)： 低温 ,  TERT ,  触媒 ,  アシル化 ,  エステル交換反応