Art

J-GLOBAL ID：201602249910126735   Reference number：16A0596160

Concise Asymmetric Construction of C₂-symmetric 1,9-Diarylnonanoids Using a Hypervalent Silicon Complex: Total Synthesis of (-)-Ericanone

超原子価ケイ素錯体を使ったC₂対称性1,9-ジアリールノナノイド類の簡潔な不斉構築: (-)-エリカノンの全合成

Author (9)： Kotani Shunsuke (Graduate School of Pharmaceutical Sciences, Kumamoto University, 5-1 Oe-honmachi, Chuo-ku, Kumamoto, 862-0973, Japan. [e-mail]) ,  Kotani Shunsuke (Priority Organization for Innovation and Excellence, Kumamoto University, 5-1 Oe-honmachi, Chuo-ku, Kumamoto, 862-0973, Japan. [e-mail]) ,  Kai Kosuke (Graduate School of Pharmaceutical Sciences, Kumamoto University, 5-1 Oe-honmachi, Chuo-ku, Kumamoto, 862-0973, Japan) ,  Shimoda Yasushi (Graduate School of Pharmaceutical Sciences, Kumamoto University, 5-1 Oe-honmachi, Chuo-ku, Kumamoto, 862-0973, Japan) ,  Hu Hao (Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita 21, Nishi 10, Kita-ku, Sapporo, 001-0021, Japan) ,  Gao Shen (Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita 21, Nishi 10, Kita-ku, Sapporo, 001-0021, Japan) ,  Sugiura Masaharu (Graduate School of Pharmaceutical Sciences, Kumamoto University, 5-1 Oe-honmachi, Chuo-ku, Kumamoto, 862-0973, Japan) ,  Ogasawara Masamichi (Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita 21, Nishi 10, Kita-ku, Sapporo, 001-0021, Japan) ,  Nakajima Makoto (Graduate School of Pharmaceutical Sciences, Kumamoto University, 5-1 Oe-honmachi, Chuo-ku, Kumamoto, 862-0973, Japan. [e-mail])
Material： Chemistry. Asian Journal  (Chem Asian J)
Volume： 11  Issue： 3  Page： 376-379  Publication year： 2016 
JST Material Number： W1856A  ISSN： 1861-4728  CODEN： CAAJBI  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： total synthesis ,  *Ericaceae ,  *metabolite ,  symmetric molecule ,  *aldol reaction ,  chemical compound ,  silicon complex ,  phosphine oxides ,  silicon compound ,  silicon chloride ,  aliphatic ketone ,  aliphatic aldehyde ,  substituent effect ,  catalytic reaction ,  hypervalent compound ,  asymmetric total synthesis ,  organic catalysis ,  Tetrachlorosilane ,  aromatic compound ,  unsaturated aldehyde ,  olefin compound
Semi thesaurus term： *Erica cinerea ,  *二重アルドール反応 ,  Silicon tetrachloride

Author keywords (5)： 19-diarylnonanoids ,  aldol reaction ,  C2-symmetry ,  hypervalent silicon complex ,  phosphine oxides

JST classification (2)： Other natural substances of biological origin  (CF10090R) ,  Plant biochemistry  (EH01050J)

Substance index (6)： (3R,7R)-1,9-Bis[4-(4-nitrophenylsulfonyloxy)phenyl]-3,7-dihydroxy-1,8-nonadiene-5-one ,  (S)-4,4′-TIPS₂-BINAPO ,  (S)-BINAPO ,  (-)-Ericanone ,  Acetone ,  Cinnamaldehyde

Terms in the title (7)： 原子価 ,  ケイ素錯体 ,  C2 ,  対称性 ,  構築 ,  カノン ,  全合成