Art

J-GLOBAL ID：201602252236028631   Reference number：16A0836344

On the Lewis base-promoted alkynylation of electron-deficient fluorobenzenes with trimethylsilylacetylenes

トリメチルシリルアセチレンを用いた電子不足性フルオロベンゼンのLewis塩基促進型アルキニル化に関して

Author (3)： Sanji Takanobu (Iyoda Supra-Integrated Material Project (iSIM), Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), and Tokyo Institute of Technology, 4259-S2-3 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan) ,  Watanabe Satoru (Iyoda Supra-Integrated Material Project (iSIM), Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), and Tokyo Institute of Technology, 4259-S2-3 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan) ,  Iyoda Tomokazu (Iyoda Supra-Integrated Material Project (iSIM), Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), and Tokyo Institute of Technology, 4259-S2-3 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 57  Issue： 17  Page： 1921-1924  Publication year： Apr. 27, 2016 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *alkynylation ,  Lewis base ,  *aromatic fluorine compound ,  selectivity ,  regiospecific reaction ,  *Fluorobenzenes ,  regioselectivity ,  crown ether
Semi thesaurus term： location-selectivity

Author keywords (4)： S_NAr ,  Lewis base ,  Alkynylation ,  Fluorobenzene

JST classification (1)： Organic reactions in general  (CF02010Q)

Substance index (15)： Ethynyltrimethylsilane ,  (p-Anisylethynyl)trimethylsilane ,  1-Phenyl-2-(pentafluorophenyl)ethyne ,  1-(Phenylethynyl)-2,3,5,6-tetrafluoro-4-[(4-methoxyphenyl)ethynyl]benzene ,  1,4-Bis(phenylethynyl)-2,3,5,6-tetrafluorobenzene ,  1-(Phenylethynyl)-2,3,5,6-tetrafluoro-4-[[4-(trifluoromethyl)phenyl]ethynyl]benzene ,  1,3-Difluoro-2-[(4-methoxyphenyl)ethynyl]-5-(phenylethynyl)benzene ,  1,3-Difluoro-2-tert-butoxy-5-(phenylethynyl)benzene ,  1,3-Difluoro-2,5-bis(phenylethynyl)benzene ,  1,3-Difluoro-2-[[4-(trifluoromethyl)phenyl]ethynyl]-5-(phenylethynyl)benzene ,  1,3-Difluoro-2-ethoxy-5-(phenylethynyl)benzene ,  1,3-Difluoro-5-[(4-methoxyphenyl)ethynyl]-2-(phenylethynyl)benzene ,  1,5-Difluoro-2-[(4-methoxyphenyl)ethynyl]-3-(phenylethynyl)benzene ,  1-[(4-Methoxyphenyl)ethynyl]-2-fluoro-4-(phenylethynyl)benzene ,  18-Crown-6

Terms in the title (6)： トリメチルシリルアセチレン ,  電子 ,  フルオロベンゼン ,  Lewis塩基 ,  促進 ,  アルキニル化