Art

J-GLOBAL ID：201602258384669799   Reference number：16A0624149

Synthesis and Chiroptical Properties of a Ring-Fused BODIPY with a Skewed Chiral π Skeleton

捻じれたキラルπ骨格を持つ縮環BODIPYの合成とカイロオプティカル特性

Author (4)： GOBO Yuki (Univ. Tsukuba, Ibaraki, JPN) ,  YAMAMURA Masaki (Univ. Tsukuba, Ibaraki, JPN) ,  NAKAMURA Takashi (Univ. Tsukuba, Ibaraki, JPN) ,  NABESHIMA Tatsuya (Univ. Tsukuba, Ibaraki, JPN)
Material： Organic Letters  (Org Lett)
Volume： 18  Issue： 11  Page： 2719-2721  Publication year： Jun. 03, 2016 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *boron heterocyclic compound ,  *nitrogen heterocyclic compound ,  *polynuclear aromatic compound ,  *optical activity ,  *cyclization reaction ,  *aromatic iodine compound ,  *oxidation ,  ultraviolet and visible absorption spectrum ,  X-ray structural analysis ,  crystal structure ,  circular dichroism spectrum ,  optically rotatory dispersion ,  circular dichroism ,  density functional method ,  quantum yield ,  fluorescence spectrum ,  optical resolution ,  absolute configuration
Semi thesaurus term： *BODIPY derivatives ,  Cotton effect ,  X-ray crystallography ,  fluorescence quantum yield ,  time-dependent density functional method ,  *hypervalent iodine compound ,  electronic circular dichroism

JST classification (2)： Cyclization reaction,ring-opening reaction  (CF02050I) ,  Organoboron compounds  (CF08020R)

Substance index (6)： Trifluoroboron・diethyl ether ,  4,4-Difluoro-2,6-bis(4,5-dimethoxy-2-methylphenyl)-8-mesityl-3a-azonia-4a-aza-4-bora(IV)-s-indacene ,  PIFA ,  4,4-Difluoro-2,3:6,5-bis[4-methyl-2,1-phenylene-[(1R)-1-methyl-5-methoxy-4-oxo-2,5-cyclohexadiene-2,1-diyl]]-8-mesityl-3a-azonia-4a-aza-4-bora(IV)-s-indacene ,  4,4-Difluoro-2,3:6,5-bis[4-methyl-2,1-phenylene-[(1S)-1-methyl-5-methoxy-4-oxo-2,5-cyclohexadiene-2,1-diyl]]-8-mesityl-3a-azonia-4a-aza-4-bora(IV)-s-indacene ,  4,4-Difluoro-2,3-[4-methyl-2,1-phenylene-[(1R)-1-methyl-5-methoxy-4-oxo-2,5-cyclohexadiene-2,1-diyl]]-6,5-[4-methyl-2,1-phenylene-[(1S)-1-methyl-5-methoxy-4-oxo-2,5-cyclohexadiene-2,1-diyl]]-8-mesityl-3a-azonia-4a-aza-4-bora(IV)-s-indacene

Terms in the title (4)： キラル ,  骨格 ,  環 ,  BODIPY