Art

J-GLOBAL ID：201602268155306736   Reference number：16A1227472

A Novel Abnormal Michael Reaction of 2-Acylmethyl-4,4-dimethyl-2-oxazolines with Acetylenic Ketones and Esters

2-アシルメチル-4,4-ジメチル-2-オキサゾリンとアセチレン性ケトン及びエステルとの新規な異常Michael反応

Author (3)： Tohda Yasuo (Center for Science Education, Osaka Kyoiku University) ,  Yanagidani Takeshi (Department of Material Science, Division of Arts and Science, Osaka Kyoiku University) ,  Asaka Noriko (Center for Science Education, Osaka Kyoiku University)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 89  Issue： 7  Page： 810-822(J-STAGE)  Publication year： 2016 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *Michael reaction ,  organic compound ,  *acetylenic compound ,  reaction mechanism ,  oxygen heterocyclic compound ,  nitrogen heterocyclic compound ,  ketone ,  *oxazolines ,  *activated methylene compound ,  *Pyridones ,  aromatic hydrocarbon
Semi thesaurus term： *Pyridones

JST classification (2)： Alkynes  (CF03040E) ,  Oxazoles,isoxazoles  (CF07080Y)

Substance index (5)： Diphenylacetylene ,  1-(4,4-Dimethyloxazolidine-2-ylidene)-3,3-dimethyl-2-butanone ,  2,2,6,6-Tetramethyl-4-[1-phenyl-2-(4,4-dimethyl-2-oxazoline-2-yl)ethenyl]heptane-3,5-dione ,  1-(1,1-Dimethyl-2-hydroxyethyl)-4-phenyl-5-pivaloyl-6-methyl-1,2-dihydropyridine-2-one ,  3,3,8a-Trimethyl-7-phenyl-2,3,6,8a-tetrahydro-8-pivaloyl-5H-oxazolo[3,2-a]pyridine-5-one

Reference (26)：

• 1) R. M. Acheson, Acc. Chem. Res. 1971, 4, 177.
• 2) N. E. Holden, A. Lapworth, J. Chem. Soc. 1931, 2368;
•  G. A. Swan, J. Chem. Soc. 1955, 1039;
•  K. Buggle, G. P. Hughes, E. M. Philbin, Chem. Ind. (London) 1969, 77.
• 3) M. M. Abou-Elzahab, S. N. Ayyad, M. T. Zimaity, Z. Naturforsch., B: Chem. Sci. 1986, 41, 363;

Terms in the title (6)： ジメチル ,  2-オキサゾリン ,  アセチレン ,  ケトン ,  エステル ,  Michael反応