Art
J-GLOBAL ID：201602282502989861   Reference number：16A1011810

Regioselective and Stereospecific Dehydrogenative Annulation Utilizing Silylium Ion-Activated Alkenes

シリリウムイオン活性化アルケン類を用いた位置選択性で立体特異的脱水素アンヌレーション
Author (7)：
ARII Hidekazu

About ARII Hidekazu

(Univ. Miyazaki, Miyazaki, JPN)

About Univ. Miyazaki, Miyazaki, JPN

, 
YANO Yuto

About YANO Yuto

(Univ. Miyazaki, Miyazaki, JPN)

About Univ. Miyazaki, Miyazaki, JPN

, 
NAKABAYASHI Kenichi

About NAKABAYASHI Kenichi

(Univ. Miyazaki, Miyazaki, JPN)

About Univ. Miyazaki, Miyazaki, JPN

, 
YAMAGUCHI Syuhei

About YAMAGUCHI Syuhei

(Ehime Univ., Ehime, JPN)

About Ehime Univ., Ehime, JPN

, 
YAMAMURA Masaki

About YAMAMURA Masaki

(Univ. Tsukuba, Ibaraki, JPN)

About Univ. Tsukuba, Ibaraki, JPN

, 
MOCHIDA Kunio

About MOCHIDA Kunio

(Gakushuin Univ., Tokyo, JPN)

About Gakushuin Univ., Tokyo, JPN

, 
KAWASHIMA Takayuki

About KAWASHIMA Takayuki

(Gunma Univ., Gunma, JPN)

About Gunma Univ., Gunma, JPN


Material：
Journal of Organic Chemistry  (J Org Chem)

About Journal of Organic Chemistry


Volume： 81  Issue： 15  Page： 6314-6319  Publication year： Aug. 05, 2016 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)
Thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
chemical reaction

About chemical reaction

, 
stereospecific reaction

About stereospecific reaction

, 
*annulation

About annulation

, 
dehydrogenation

About dehydrogenation

, 
alkene

About alkene

, 
*silanes

About silanes

, 
*organosilicon compound

About organosilicon compound

, 
aromatic compound

About aromatic compound

, 
polynuclear aromatic compound

About polynuclear aromatic compound

, 
polynuclear aromatic hydrocarbon

About polynuclear aromatic hydrocarbon

, 
cation

About cation

, 
Friedel-Crafts reaction

About Friedel-Crafts reaction

, 
reaction mechanism

About reaction mechanism

, 
*heterocyclic compound

About heterocyclic compound

, 
ion

About ion

, 
silicon

About silicon


Semi thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
silicon ion

About silicon ion

, 
naphthalene derivative

About naphthalene derivative

, 
Phenalenes

About Phenalenes

, 
Benzyl Compounds

About Benzyl Compounds

, 
regioselective reaction

About regioselective reaction

, 
*organic silane derivative

About organic silane derivative


JST classification (3)：
JST classification
Category name(code) classified by JST.
Cyclization reaction,ring-opening reaction 
(CF02050I)

About Cyclization reaction,ring-opening reaction

,  Organosilicon compounds 
(CF08030C)

About Organosilicon compounds

,  Heterocyclic compounds in general 
(CF07010Z)

About Heterocyclic compounds in general

Substance index (11)：
Substance index
Chemical Substance indexed to the Article.
2,7-Di-tert-butyl-9,9-diphenyl-9-sila-9H-fluorene

About 2,7-Di-tert-butyl-9,9-diphenyl-9-sila-9H-fluorene

, 
3β-Trimethylsilyl-2-silatetralin

About 3β-Trimethylsilyl-2-silatetralin

, 
4α-Butyl-2-silatetralin

About 4α-Butyl-2-silatetralin

, 
4α-Hexyl-2-silatetralin

About 4α-Hexyl-2-silatetralin

, 
3β,4α-Dipropyl-2-silatetralin

About 3β,4α-Dipropyl-2-silatetralin

, 
1,1-Diisopropyl-3α-butyl-1-sila-2,3-dihydro-1H-phenalene

About 1,1-Diisopropyl-3α-butyl-1-sila-2,3-dihydro-1H-phenalene

, 
1,1-Diisopropyl-3α-hexyl-1-sila-2,3-dihydro-1H-phenalene

About 1,1-Diisopropyl-3α-hexyl-1-sila-2,3-dihydro-1H-phenalene

, 
1,1-Diisopropyl-2β,3α-dipropyl-1-sila-2,3-dihydro-1H-phenalene

About 1,1-Diisopropyl-2β,3α-dipropyl-1-sila-2,3-dihydro-1H-phenalene

, 
1,1-Diisopropyl-2β,3β-butano-1-sila-2,3-dihydro-1H-phenalene

About 1,1-Diisopropyl-2β,3β-butano-1-sila-2,3-dihydro-1H-phenalene

, 
1,1-Diisopropyl-2β,3α-diethyl-1-sila-2,3-dihydro-1H-phenalene

About 1,1-Diisopropyl-2β,3α-diethyl-1-sila-2,3-dihydro-1H-phenalene

, 
1,1-Diisopropyl-2β,3β-diethyl-1-sila-2,3-dihydro-1H-phenalene

About 1,1-Diisopropyl-2β,3β-diethyl-1-sila-2,3-dihydro-1H-phenalene

Terms in the title (5)：
Terms in the title
Keywords automatically extracted from the title.
活性化

About 活性化

, 
アルケン

About アルケン

, 
位置選択性

About 位置選択性

, 
脱水素

About 脱水素

, 
アンヌレーション

About アンヌレーション


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