Art

J-GLOBAL ID：201602287231844418   Reference number：16A1195821

One-Pot Halogen Dance/Negishi Coupling of Dibromothiophenes for Regiocontrolled Synthesis of Multiply Arylated Thiophenes

複数アリール化したチオフェンを位置制御合成するためのジブロモチオフェン類のワンポットハロゲンダンス/Negishiカップリング

Author (5)： Okano Kentaro (Department of Chemical Science and Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe, 657-8501, Japan. [e-mail]) ,  Sunahara Kazuhiro (Department of Chemical Science and Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe, 657-8501, Japan) ,  Yamane Yoshiki (Department of Chemical Science and Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe, 657-8501, Japan) ,  Hayashi Yuki (Department of Chemical Science and Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe, 657-8501, Japan) ,  Mori Atsunori (Department of Chemical Science and Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe, 657-8501, Japan)
Material： Chemistry - European Journal  (Chem Eur J)
Volume： 22  Issue： 46  Page： 16450-16454  Publication year： 2016 
JST Material Number： W0744A  ISSN： 0947-6539  CODEN： CEUJED  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： catalytic reaction ,  palladium catalyst ,  palladium complex ,  *cross coupling reaction ,  Suzuki reaction ,  exchange reaction ,  *rearrangement reaction ,  *sulfur heterocyclic compound ,  organobromine compound ,  aromatic compound ,  one-pot synthesis ,  lithiation ,  metal exchange reaction ,  Negishi coupling ,  Thiophenes
Semi thesaurus term： Negishi coupling reaction ,  Suzuki-Miyaura coupling reactions ,  Thiophenes ,  ハロゲンダンス反応

Author keywords (5)： cross-coupling ,  halogen dance ,  one-pot reaction ,  palladium ,  thiophene

JST classification (2)： Thiophenes  (CF07074D) ,  Catalytic reactions in general  (CB06080F)

Substance index (18)： 2,3-Bis(3-methoxyphenyl)-5-phenylthiophene ,  2,4-Dibromothiophene ,  2,4-Dibromo-3-(4-chlorophenyl)-5-[4-(trifluoromethyl)phenyl]thiophene ,  2,4-Dibromo-3-(4-chlorophenyl)-5-phenylthiophene ,  2,4-Dibromo-3-(4-methoxyphenyl)-5-(4-nitrophenyl)thiophene ,  2,4-Dibromo-3-(4-methoxyphenyl)-5-[4-(trifluoromethyl)phenyl]thiophene ,  2,4-Dibromo-3-(4-methoxyphenyl)-5-phenylthiophene ,  2,5-Dibromothiophene ,  2,5-Bis(3-methoxyphenyl)-3-phenylthiophene ,  2-(4-tert-Butylphenyl)-3-(4-methoxyphenyl)-4-phenyl-5-[4-(trifluoromethyl)phenyl]thiophene ,  2-(4-Methoxyphenyl)-3,5-dibromothiophene ,  2-Phenyl-3-(4-chlorophenyl)-4-(4-methylphenyl)-5-[4-(trifluoromethyl)phenyl]thiophene ,  2-Phenyl-3-(4-methoxyphenyl)-4-(4-tert-butylphenyl)-5-[4-(trifluoromethyl)phenyl]thiophene ,  2-Phenyl-3-(4-methoxyphenyl)-4-(4-methylphenyl)-5-[4-(trifluoromethyl)phenyl]thiophene ,  4′-[2-(4-Nitrophenyl)-4-(4-chlorophenyl)-5-phenyl-3-thienyl]acetophenone ,  4-[3,5-Dibromo-4-(4-methoxyphenyl)-2-thienyl]benzoic acid ethyl ester ,  4-[3-(4-Nitrophenyl)-4-(4-methoxyphenyl)-5-phenyl-2-thienyl]benzoic acid ethyl ester ,  LDA (reagent)

Terms in the title (4)： アリール化 ,  チオフェン ,  位置制御 ,  Negishiカップリング

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© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim