Art

J-GLOBAL ID：201602290480339392   Reference number：16A0717178

Enantioselective Synthesis of Silacyclopentanes

シラシクロペンタン類のエナンチオ選択的合成

Author (4)： Igawa Kazunobu (Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka, 816-8580, Japan. [e-mail]) ,  Yoshihiro Daisuke (Department of Molecular and Material Sciences, Kyushu University, Japan) ,  Abe Yusuke (Department of Molecular and Material Sciences, Kyushu University, Japan) ,  Tomooka Katsuhiko (Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka, 816-8580, Japan. [e-mail])
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 55  Issue： 19  Page： 5814-5818  Publication year： 2016 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *alicyclic hydrocarbon ,  organosilicon compound ,  asymmetric synthesis ,  chemical synthesis ,  *elimination reaction ,  stereospecific reaction ,  density functional method ,  reaction mechanism ,  biological activity ,  silicon ,  property ,  serotonin receptor ,  *silicon heterocyclic compound ,  enantioselective synthesis ,  stereospecific synthesis ,  chirality ,  *Cyclopentanes
Semi thesaurus term： DFT calculation ,  chirality ,  *Cyclopentanes ,  silicon

Author keywords (5)： asymmetric synthesis ,  biological activity ,  chirality ,  elimination ,  silicon

JST classification (3)： Cyclopentanes  (CF04040L) ,  Addition reaction,elimination reaction  (CF02030M) ,  Organosilicon compounds  (CF08030C)

Substance index (13)： 1α-tert-Butyl-1-phenyl-1-silacyclopentane-4-ene-3β-ol ,  (1S)-4α-Methyl-4β-phenyl-4-sila-2-cyclopentene-1β-ol ,  (1S)-4α-Phenyl-4β-methyl-4-sila-2-cyclopentene-1β-ol ,  (1S)-4α-(tert-Butyl)-4β-(3,5-xylyl)-4-sila-2-cyclopentene-1β-ol ,  (1S)-4α-(tert-Butyl)-4β-benzyloxy-4-sila-2-cyclopentene-1β-ol ,  (1S)-4α-(tert-Butoxy)-4β-phenyl-4-sila-2-cyclopentene-1β-ol ,  2-[(1S)-4α-(tert-Butyl)-4β-phenyl-4-sila-2-cyclopentene-1β-yl]malonic acid dimethyl ester ,  (1S)-4α-(tert-Butyl)-4β-phenyl-2β,3β-methano-4-silacyclopentane-1β-ol ,  (1S)-3α-Azido-4α-(tert-butyl)-4β-phenyl-4-silacyclopentane-1β,2β-diol ,  (1S)-3α-Bromo-4α-(tert-butyl)-4β-phenyl-4-silacyclopentane-1β,2β-diol ,  (1S)-4α-(tert-Butyl)-4β-phenyl-4-silacyclopentane-1β,2β,3α-triol ,  (1S)-4α-Phenyl-4β-(tert-butyl)-4-silacyclopentane-1β,2β,3α-triol ,  (1S)-4α-Methyl-4β-phenyl-4-silacyclopentane-1β,2β,3α-triol

Terms in the title (2)： シラシクロペンタン ,  エナンチオ選択的合成