Art

J-GLOBAL ID：201602290990430273   Reference number：16A1190526

A Ruthenium(III)-Oxyl Complex Bearing Strong Radical Character

強いラジカル特質を有するルテニウム(III)-オキシル錯体

Author (10)： Shimoyama Yoshihiro (Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki, 305-8571, Japan) ,  Ishizuka Tomoya (Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki, 305-8571, Japan) ,  Kotani Hiroaki (Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki, 305-8571, Japan) ,  Shiota Yoshihito (Institute for Materials Chemistry and Engineering, Kyushu University, Motooka, Nishi-Ku, Fukuoka, 819-0395, Japan) ,  Yoshizawa Kazunari (Institute for Materials Chemistry and Engineering, Kyushu University, Motooka, Nishi-Ku, Fukuoka, 819-0395, Japan) ,  Mieda Kaoru (Picobiology Institute, Graduate School of Life Science, University of Hyogo, RSC-UH Leading Program Center, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5148, Japan) ,  Ogura Takashi (Picobiology Institute, Graduate School of Life Science, University of Hyogo, RSC-UH Leading Program Center, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5148, Japan) ,  Okajima Toshihiro (Kyushu Synchrotron Light Research Center, 8-7 Yayoigaoka, Tosu, Saga, 841-0005, Japan) ,  Nozawa Shunsuke (Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki, 305-0801, Japan) ,  Kojima Takahiko (Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki, 305-8571, Japan. [e-mail])
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 55  Issue： 45  Page： 14041-14045  Publication year： 2016 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： catalytic reaction ,  carbene ,  nitrogen heterocyclic compound ,  *oxidation ,  aqua complex ,  *ruthenium complex ,  radical ,  *ruthenium catalyst ,  chloride ,  perchlorate ,  N-heterocyclic carbene ,  aliphatic ketone ,  aliphatic alcohol ,  aromatic aldehyde ,  aromatic carboxylic acid
Semi thesaurus term： NHC

Author keywords (5)： catalysis ,  N-heterocyclic carbenes ,  oxyl radicals ,  ruthenium ,  substrate oxidation

JST classification (2)： Platinum family element complexes  (CE01100E) ,  Nobel metal catalysts  (CB06122I)

Substance index (6)： 1,3-Bis(2-pyridylmethyl)4-imidazoline ,  2,2'-Dipyridyl ,  Acetone ,  2-Propanol ,  Benzaldehyde ,  Benzoic Acid

Terms in the title (4)： ラジカル ,  特質 ,  ルテニウム ,  錯体