Art

J-GLOBAL ID：201702211102587206   Reference number：17A1608275

Asymmetric Desymmetrization of Substituted Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation and Theoretical Calculations of Its Mechanistic Aspects

ロジウム触媒共役ヒドロシリル化による置換シクロヘキサジエノン類の不斉脱対称およびその機構的側面の理論的計算

Author (4)： NAGANAWA Yuki (National Inst. of Advanced Industrial Sci. and Technol. (AIST), Tsukuba, JPN) ,  ITO Jun-ichi (Nagoya Univ., Nagoya, JPN) ,  KAWAGISHI Mayu (Nagoya Univ., Nagoya, JPN) ,  NISHIYAMA Hisao (Nagoya Univ., Nagoya, JPN)
Material： Synthesis  (Journal of Synthetic Organic Chemistry)
Volume： 49  Issue： 19  Page： 4448-4460  Publication year： Oct. 04, 2017 
JST Material Number： D0738A  ISSN： 0039-7881  CODEN： SYNTBF  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： rhodium catalyst ,  catalytic reaction ,  *hydrosilylation ,  enone ,  *alicyclic ketone ,  asymmetric synthesis ,  organosilicon compound ,  rhodium complex ,  calculation ,  theory ,  spiro-compound
Semi thesaurus term： dienone ,  hydrosilane ,  theoretical calculation

JST classification (3)： Catalytic reactions in general  (CB06080F) ,  Stereochemistry of organic reaction  (CF02130V) ,  Cyclohexanes  (CF04050W)

Substance index (15)： 4α-Methyl-4-phenyl-2-cyclohexene-1-one ,  4α-Methyl-4-(4-methylphenyl)-2-cyclohexene-1-one ,  4α-Methyl-4-(3-methylphenyl)-2-cyclohexene-1-one ,  4α-Methyl-4-(2-methylphenyl)-2-cyclohexene-1-one ,  4α-Methyl-4-(4-methoxyphenyl)-2-cyclohexene-1-one ,  4α-Methyl-4-[4-(trifluoromethyl)phenyl]-2-cyclohexene-1-one ,  4α-Methyl-4-(1-naphthyl)-2-cyclohexene-1-one ,  4α-Ethyl-4-phenyl-2-cyclohexene-1-one ,  (S)-Spiro[2-cyclohexene-1,1′-tetralin]-4-one ,  (S)-7′-Methoxyspiro[2-cyclohexene-1,1′-tetralin]-4-one ,  (S)-7′-Fluorospiro[2-cyclohexene-1,1′-tetralin]-4-one ,  (S)-7′-Chlorospiro[2-cyclohexene-1,1′-tetralin]-4-one ,  (S)-6′-Methoxyspiro[2-cyclohexene-1,1′-tetralin]-4-one ,  (S)-6′-Chlorospiro[2-cyclohexene-1,1′-tetralin]-4-one ,  (S)-5′-Methoxyspiro[2-cyclohexene-1,1′-tetralin]-4-one

Terms in the title (7)： ロジウム触媒 ,  共役 ,  ヒドロシリル化 ,  置換 ,  対称 ,  理論 ,  計算