Art

J-GLOBAL ID：201702215482620804   Reference number：17A1921414

Palladium-catalyzed Benzylic Substitution of Benzyl Carbonates with Phosphorus Nucleophiles

炭酸ベンジルのリン求核試薬によるパラジウム触媒ベンジル置換

Author (5)： Makida Yusuke (Department of Chemistry, Faculty of Science, Kyushu University) ,  Usui Kazumi (Department of Chemistry, Faculty of Science, Kyushu University) ,  Ueno Satoshi (Department of Chemistry, Faculty of Science, Kyushu University) ,  Ueno Satoshi (Department of Applied Chemistry, School of Engineering, Tokyo University of Technology) ,  Kuwano Ryoichi (Department of Chemistry, Faculty of Science, Kyushu University)
Material： Chemistry Letters  (Chem Lett)
Volume： 46  Issue： 12  Page： 1814-1817(J-STAGE)  Publication year： 2017 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *nucleophilic reagent ,  *palladium catalyst ,  *substitution reaction ,  palladium complex ,  proton magnetic resonance ,  solvent effect ,  ligand effect ,  allyl complex ,  chloro complex ,  catalytic reaction ,  aliphatic carboxylic acid ,  carboxamide ,  aromatic aldehyde

Author keywords (3)： Palladium catalyst ,  Benzylic substitution ,  Phosphorus nucleophiles

JST classification (3)： Substitution reaction  (CF02020B) ,  Catalytic reactions(homogeneous system)  (CB06090Q) ,  Organop phosphorus compounds  (CF08040N)

Substance index (9)： Carbonic acid methylbenzyl ester ,  Phosphonic acid dimethyl ,  Diphenylphosphine oxide ,  Dimethylformamide ,  Benzyldiphenylphosphine oxide ,  Benzaldehyde ,  DPEphos ,  Dimethyl benzylphosphonate ,  (E)-4-Methoxystilbene

Reference (53)：

• 1) B. E. Maryanoff, A. B. Reitz, Chem. Rev. 1989, 89, 863.
• 2) a) R. Noyori, Angew. Chem., Int. Ed. 2002, 41, 2008.
• 2) b) D. H. Valentine, Jr., J. H. Hillhouse, Synthesis 2003, 2437.
• 2) c) R. C. J. Atkinson, V. C. Gibson, N. J. Long, Chem. Soc. Rev. 2004, 33, 313.
• 3) a) P. Kafarski, B. Lejczak, Phosphorus, Sulfur Silicon Relat. Elem. 1991, 63, 193.

Terms in the title (6)： 炭酸 ,  ベンジル ,  リン ,  求核試薬 ,  パラジウム触媒 ,  置換