Art

J-GLOBAL ID：201702221642249352   Reference number：17A1513275

Intramolecular Hydroalkoxylation/Reduction and Hydroamination/Reduction of Unactivated Alkynes Using a Silane-Iodine Catalytic System

シラン-ヨウ素触媒系を使用した不活性アルキン類の分子内ヒドロアルコキシ化/還元とヒドロアミノ化/還元

Author (3)： FUJITA Shoji (Nagoya Univ., Nagoya, JPN) ,  SHIBUYA Masatoshi (Nagoya Univ., Nagoya, JPN) ,  YAMAMOTO Yoshihiko (Nagoya Univ., Nagoya, JPN)
Material： Synthesis  (Journal of Synthetic Organic Chemistry)
Volume： 49  Issue： 18  Page： 4199-4204  Publication year： Sep. 18, 2017 
JST Material Number： D0738A  ISSN： 0039-7881  CODEN： SYNTBF  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *cyclic ether ,  *oxygen heterocyclic compound ,  addition reaction ,  amination ,  reduction(reaction) ,  alkyne ,  *catalyst ,  *silane ,  *cyclization reaction ,  *nitrogen heterocyclic compound ,  stereoselectivity
Semi thesaurus term： diastereofacial selectivity ,  *tetrahydrofuran derivative ,  hydroamination ,  hydroalkoxylation ,  *Pyrrolidines ,  *iodine catalyst ,  internal alkyne ,  *intramolecular cyclization ,  terminal alkyne

JST classification (3)： Furans  (CF07072V) ,  Pyrroles  (CF07076L) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (15)： 2-Methyl-4,4-diphenyloxolane ,  3-Methyl-2-oxaspiro[4.5]decane ,  5-Methyl-4,5-dihydrofuran-3,3(2H)-dicarboxylic acid diethyl ester ,  Benzoic acid (3-propargyl-5-methyltetrahydrofuran-3-yl)methyl ester ,  3-Ethyl-2-oxaspiro[4.5]decane ,  3-Methyl-2-oxaspiro[5.5]undecane ,  2β-Methyl-3α-pentyltetrahydrofuran ,  2β-Methyl-4β-isopropyltetrahydrofuran ,  2-Tosyl-3-methyl-2-azaspiro[4.5]decane ,  2-(2-Nitrophenylsulfonyl)-3-methyl-2-azaspiro[4.5]decane ,  1-Tosyl-2-methyl-4,4-diphenylpyrrolidine ,  Benzoic acid (1-tosyl-3-propargyl-5-methylpyrrolidine-3-yl)methyl ester ,  2-Tosyl-3-ethyl-2-azaspiro[4.5]decane ,  1-Tosyl-2β-methyl-3α-pentylpyrrolidine ,  2-Methyl-4-phenyl-4-propargyltetrahydrofuran

Terms in the title (7)： シラン ,  ヨウ素触媒 ,  不活性 ,  アルキン ,  ヒドロアルコキシ化 ,  還元 ,  ヒドロアミノ化