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J-GLOBAL ID：201702224281193405   Reference number：17A1419977

Inversions in asymmetric conjugate addition reaction of cyclic enones catalyzed by the Cu/NHC-AgX system: Factors affecting the stereoselective formation of both enantiomers

Cu/NHC AgX系触媒による環状エノン類の不斉共役付加反応における逆位:両エナンチオマの立体選択的生成に影響する因子【Powered by NICT】

Author (2)： Nakano Yuki (Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan) ,  Sakaguchi Satoshi (Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan)
Material： Journal of Organometallic Chemistry  (J Organomet Chem)
Volume： 846  Page： 407-416  Publication year： 2017 
JST Material Number： B0412C  ISSN： 0022-328X  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Abstract/Point： A switchable enantioselectivit...

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Thesaurus term： silver complex ,  chiral ligand ,  amplification phenomenon ,  functionalization ,  reaction path ,  precursor (substance) ,  *catalyst ,  halide ,  complex (compound) ,  *enone ,  ion ,  *enantiomer ,  chirality ,  enantioselectivity ,  *conjugated addition

Author keywords (5)： Asymmetric catalysis ,  Reversal of enantioselectivity ,  Conjugate addition ,  N-Heterocyclic carbene ,  Copper

JST classification (2)： Platinum family element complexes  (CE01100E) ,  Complexes of nontransition metal elements  (CE01030C)

Terms in the title (11)： Cu ,  NHC ,  AgX ,  触媒 ,  環状 ,  エノン ,  共役付加 ,  逆位 ,  エナンチオマ ,  立体 ,  因子