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J-GLOBAL ID：201702228748028778   Reference number：17A0776895

Two-electron Reduction of Diboryldiphosphene: Formation of Intramolecular Charge-transfer Complex of Dianionic B^-=P-P=B^- Species

ジボリルジホスフェンの二電子還元 ジアニオンB^-=P-P=B^-化学種の分子内電荷移動錯体の形成

Author (4)： Asami Shun-suke (Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University) ,  Suzuki Katsunori (Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University) ,  Yamashita Makoto (Department of Applied Chemistry, Graduate School of Engineering, Nagoya University) ,  Yamashita Makoto (Research Development Initiative, Chuo University)
Material： Chemistry Letters  (Chem Lett)
Volume： 46  Issue： 5  Page： 686-689(J-STAGE)  Publication year： 2017 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,  *boron heterocyclic compound ,  *phosphorus compound ,  aromatic compound ,  reduction(reaction) ,  lithium ,  lithium complex ,  methylation ,  31P NMR ,  proton magnetic resonance ,  X-ray diffraction ,  crystal structure ,  crystal structure analysis ,  density functional method ,  charge transfer ,  *charge transfer complex ,  complex formation ,  interatomic interaction ,  ultraviolet and visible absorption spectrum ,  pi-orbital ,  spectral line assignment ,  *amine ,  aliphatic iodine compound
Semi thesaurus term： Two Electron Reduction ,  11B NMR ,  7Li NMR ,  DFT calculation ,  intramolecular charge transfer

Author keywords (3)： Main group ,  Boryl-substituted diphosphene ,  Intramolecular charge transfer

JST classification (4)： Molecular compounds  (CE02000C) ,  Other 5-membered rings with two or more hetero atoms  (CF07085F) ,  Complexes of nontransition metal elements  (CE01030C) ,  Crystal structure of molecular compounds in general  (BK09050T)

Substance index (3)： Methyl iodide ,  4-(Dimethylamino)pyridine ,  1,2-Bis[1,3-bis(2,6-diisopropylphenyl)-1,3,2-diazaborolidine-2-yl]diphosphine

Reference (49)：

• 1) a) L. Weber, Chem. Rev. 1992, 92, 1839.
• 1) b) P. P. Power, Chem. Rev. 1999, 99, 3463.
• 1) c) R. C. Fischer, P. P. Power, Chem. Rev. 2010, 110, 3877.
• 1) d) T. Baumgartner, R. Réau, Chem. Rev. 2006, 106, 4681.
• 2) M. Weidenbruch, S. Willms, W. Saak, G. Henkel, Angew. Chem., Int. Ed. 1997, 36, 2503.

Terms in the title (4)： 二電子還元 ,  ジアニオン ,  化学種 ,  電荷移動錯体