Art

J-GLOBAL ID：201702230833947600   Reference number：17A0058425

Regioselective Arylative Ring-Closing Reaction of 2-Alkynylphenyl Derivatives: Formation of Arylated Benzoxazin-2-ones, Benzoxazin-2-amines and 2,3-Disubstituted Indoles

2-アルキニルフェニル誘導体の位置選択的アリール化的閉環反応:アリール化ベンゾオキサジン-2-オン類,ベンゾオキサジン-2-アミン類および2,3-二置換インドール類の生成

Author (6)： Minami Hideki (Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, 737-0112, Kure, Hiroshima, Japan) ,  Kanayama Takuya (Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, 737-0112, Kure, Hiroshima, Japan) ,  Tanaka Reishi (Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, 737-0112, Kure, Hiroshima, Japan) ,  Okamoto Noriko (Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, 737-0112, Kure, Hiroshima, Japan) ,  Sueda Takuya (Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, 737-0112, Kure, Hiroshima, Japan) ,  Yanada Reiko (Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, 737-0112, Kure, Hiroshima, Japan)
Material： European Journal of Organic Chemistry  (Eur J Org Chem)
Volume： 2016  Issue： 36  Page： 5990-6000  Publication year： 2016 
JST Material Number： W1026A  ISSN： 1434-193X  CODEN： EJOCFK  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,  molecular structure ,  *nitrogen heterocyclic compound ,  *polynuclear aromatic compound ,  *oxygen heterocyclic compound ,  *cyclization reaction ,  chemical reaction ,  copper catalyst ,  copper complex ,  palladium complex ,  palladium catalyst ,  catalytic reaction ,  acetylenic compound ,  aromatic hydrocarbon ,  reaction mechanism ,  arylation ,  aromatic iodine compound ,  aromatic carboxylic acid ,  enzyme inhibitor ,  aromatic chlorine compound ,  carboxamide ,  phenol ether
Semi thesaurus term： Indoles ,  phenylacetylenes ,  *Benzoxazines ,  regiospecific reaction ,  hypervalent iodine compound

Author keywords (6)： Regioselectivity ,  Arylation ,  Cyclization ,  Alkynes ,  Nitrogen heterocycles ,  Oxygen heterocycles

JST classification (2)： Cyclization reaction,ring-opening reaction  (CF02050I) ,  Oxazines  (CF07100X)

Substance index (17)： Indomethacin ,  N-(Ethoxycarbonyl)-2-(1-butynyl)aniline ,  1-Benzyl-1H-3,1-benzoxazine-2,4-dione ,  1-Phenyl-4-(1-phenylpentane-1-ylidene)-1H-3,1-benzooxazine-2(4H)-one ,  1-(p-Tolyl)-4-(1-(p-tolyl)pentane-1-ylidene)-1H-3,1-benzooxazine-2(4H)-one ,  1-(4-Fluorophenyl)-4-(1-(4-fluorophenyl)pentane-1-ylidene)-1H-3,1-benzooxazine-2(4H)-one ,  1-Phenyl-4-diphenylmethylene-1H-3,1-benzooxazine-2(4H)-one ,  1-Phenyl-4-((p-tolyl)phenylmethylene)-1H-3,1-benzooxazine-2(4H)-one ,  1-Phenyl-4-(1-phenylpentane-1-ylidene)-7-methyl-1H-3,1-benzooxazine-2(4H)-one ,  N-Benzyl-4-(1-phenylpentane-1-ylidene)-4H-3,1-benzooxazine-2-amine ,  2-(4-Morpholinyl)-4-(1-phenylpentane-1-ylidene)-4H-3,1-benzooxazine ,  N-Benzyl-4-(1-(p-tolyl)pentane-1-ylidene)-4H-3,1-benzooxazine-2-amine ,  N-Benzyl-4-(1-(4-fluorophenyl)pentane-1-ylidene)-4H-3,1-benzooxazine-2-amine ,  N-Benzyl-4-(1-phenylpentane-1-ylidene)-7-methyl-4H-3,1-benzooxazine-2-amine ,  2-Butyl-3-phenyl-1H-indole-1-carboxylic acid ethyl ester ,  2-Butyl-3-phenyl-1H-indole-1-carboxylic acid methyl ester ,  2-Butyl-3-(4-fluorophenyl)-1H-indole-1-carboxylic acid ethyl ester

Terms in the title (7)： 誘導体 ,  位置選択 ,  アリール化 ,  閉環反応 ,  アミン類 ,  置換 ,  インドール類