Art

J-GLOBAL ID：201702232694622268   Reference number：17A0565801

Copper-catalyzed Selective Oxygenation of Methyl and Benzyl Substituents in Pyridine with O₂

メチル及びベンジル置換基の銅触媒選択酸素化

Author (6)： Abe Tsukasa (Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University) ,  Tanaka Shinji (Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)) ,  Ogawa Atsuko (Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)) ,  Tamura Masanori (Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)) ,  Sato Kazuhiko (Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST)) ,  Itoh Shinobu (Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University)
Material： Chemistry Letters  (Chem Lett)
Volume： 46  Issue： 3  Page： 348-350(J-STAGE)  Publication year： 2017 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *copper catalyst ,  *oxygenation ,  *selectivity ,  *alkyl group ,  *benzyl group ,  nitrogen heterocyclic compound ,  oxidizing agent ,  copper chloride ,  Oxygen ,  diatomic molecule ,  aldehyde ,  ketone ,  Water ,  additive effect ,  catalytic activity ,  proton ,  donor ,  reaction mechanism ,  Picolines ,  *methyl group ,  dioxygen
Semi thesaurus term： proton ,  molecular oxygen

Author keywords (3)： Copper-catalyzed oxygenation ,  Molecular oxygen ,  Picoline

JST classification (2)： Oxidation,reduction  (CF02060T) ,  Catalytic reactions(homogeneous system)  (CB06090Q)

Substance index (6)： 2-Methylpyridine ,  Pyridine-2-carbaldehyde ,  4-Methylpyridine ,  4-Pyridinecarbaldehyde ,  4-Benzylpyridine ,  4-Benzoylpyridine

Reference (27)：

• 1) Modern Oxidation Methods, ed. by J.-E. Bäckvall, Wiley-VCH, Weinheim, 2010. doi:10.1002/9783527632039.
• 2) E. Vitaku, D. T. Smith, J. T. Njardarson, J. Med. Chem. 2014, 57, 10257.
• 3) J.-J. Shie, J.-M. Fang, J. Org. Chem. 2003, 68, 1158.
• 4) A. K. Yadav, V. P. Srivastava, L. D. S. Yadav, Synth. Commun. 2014, 44, 408.
• 5) a) A. Shibamoto, S. Sakaguchi, Y. Ishii, Org. Process Res. Dev. 2000, 4, 505.

Terms in the title (4)： ベンジル ,  置換基 ,  銅触媒 ,  酸素化