Art

J-GLOBAL ID：201702234281257166   Reference number：17A0918451

Development of Neighboring Electrophilic Activation of Active Center in Catalytic Reactions via Organometallic Intermediates

有機金属中間体による触媒反応における活性中心の近隣求電子活性化の発展

Author (1)： Endo Kohei (Department of Chemistry, Faculty of Science, Tokyo University of Science)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 90  Issue： 6  Page： 649-661(J-STAGE)  Publication year： 2017 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： catalytic reaction ,  reagent ,  organozinc compound ,  X-ray structural analysis ,  cycloalkene ,  silver catalyst ,  allylation ,  reaction mechanism ,  NMR ,  *coupling reaction ,  addition reaction ,  copper catalyst ,  ligand effect ,  atom ,  stereochemistry ,  *ester ,  *organic boron acid ,  cyclopropenes ,  11B NMR ,  organozinc reagent ,  stereocenter ,  1,4-addition ,  X-ray crystallographic analysis ,  *boronic acid ester
Semi thesaurus term： 1,4-addition reaction ,  X-ray crystallography ,  *boronic ester

JST classification (2)： Organoboron compounds  (CF08020R) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (30)： (1R,2R)-1,2-Dihydro-2,5,8-trimethyl-1-naphthol ,  (1R,2R)-1,2-Dihydro-5,8-dimethoxy-2-methyl-1-naphthol ,  (1S,2R)-2-[2-(1-Butenyl)-5,5-dimethyl-1,3-dioxane-2-yl]-N,N-diethyl-2-(2,2-dimethylhydrazino)-5,5-dimethylcyclohexanecarboxamide ,  (1S,2R,4S)-2-[2-(1-Butenyl)-5,5-dimethyl-1,3-dioxane-2-yl]-N,N-diethyl-2-(2,2-dimethylhydrazino)-4-methylcyclohexanecarboxamide ,  (S)-β-Phenylvalerophenone ,  (3S)-3-(2-Naphthyl)-1-phenyl-1-pentanone ,  (5R)-6α-Methyl-5,6-dihydronaphtho[2,3-d]-1,3-dioxole-5α-ol ,  1,1-Dibenzyl-2-ethyl-4-phenyl-3-pentene-1-ol ,  1-(1-Methyl-1-phenyl-2-pentenyl)cyclohexanol ,  1-(1-Methyl-1-phenyl-2-pentenyl)cyclopentanol ,  2-[1-(3,5-Dimethylphenyl)-5-phenylpentyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-[1-(4-Methylphenyl)-5-phenylpentyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  1-(4-Chlorophenyl)-3-methyl-3-phenyl-1-pentanone ,  2-[4-(2-Morpholinoethoxy)phenyl]-1,3-diphenyl-2-pentene ,  1,2-Diphenyl-2-methyl-3-hexene-1-ol ,  3-(4-Biphenylyl)-3-methyl-1-phenyl-1-pentanone ,  3-Ethyl-3,5-diphenyl-2(3H)-furanone ,  3-Ethyl-5-(2-naphthyl)-3-methyl-2(3H)-furanone ,  3-Ethyl-5-(4-chlorophenyl)-3-methyl-2(3H)-furanone ,  3-Methyl-1,3-diphenyl-1-octanone ,  3-Methyl-1,3-diphenyl-1-pentanone ,  3-Methyl-3,5-diphenyl-2(3H)-furanone ,  4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-methylphenyl)-1-butene ,  4-(3-Methylbenzyl)anisole ,  4-(4-Methylbenzyl)anisole ,  α-[2-(1-Butenyl)-5,5-dimethyl-1,3-dioxane-2-yl]-2-furanmethanol ,  α-[2-(1-Butenyl)-5,5-dimethyl-1,3-dioxane-2-yl]-4-methylbenzyl alcohol ,  α-[2-(1-Butenyl)-5,5-dimethyl-1,3-dioxane-2-yl]-4-methoxybenzyl alcohol ,  β-(4-Chlorophenyl)butyrophenone ,  β-Cyclohexylbutyrophenone

Reference (105)：

• 1) P. Buchwalter, J. Rosé, P. Braunstein, Chem. Rev. 2015, 115, 28.
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• 3) b) M. Devillard, R. Declercq, E. Nicolas, A. W. Ehlers, J. Backs, N. Saffon-Merceron, G. Bouhadir, J. C. Slootweg, W. Uhl, D. Bourissou, J. Am. Chem. Soc. 2016, 138, 4917.

Terms in the title (7)： 有機金属 ,  中間体 ,  触媒反応 ,  活性中心 ,  電子 ,  活性化 ,  発展