Art

J-GLOBAL ID：201702234284900419   Reference number：17A1366865

π-Allyl Donicity Switch in Catalytic Asymmetric Allylation: Usability of a Robust and Feasible Allyl Methyl Ether

触媒不斉アリル化でのπ-アリル供与性転換 堅牢で実行可能なアリルメチルエーテルの有用性

Author (5)： Suzuki Yusuke (Graduate School of Pharmaceutical Sciences and Research Center for Materials Science, Nagoya University) ,  Iwase Shoutaro (Graduate School of Pharmaceutical Sciences and Research Center for Materials Science, Nagoya University) ,  Hashimoto Kazuki (Graduate School of Pharmaceutical Sciences and Research Center for Materials Science, Nagoya University) ,  Tanaka Shinji (Graduate School of Pharmaceutical Sciences and Research Center for Materials Science, Nagoya University) ,  Kitamura Masato (Graduate School of Pharmaceutical Sciences and Research Center for Materials Science, Nagoya University)
Material： Chemistry Letters  (Chem Lett)
Volume： 46  Issue： 9  Page： 1308-1310(J-STAGE)  Publication year： 2017 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *catalytic reaction ,  *asymmetric synthesis ,  *allylation ,  group(radical) ,  *reactivity ,  complex(compound) ,  asymmetric catalyst ,  *ruthenium catalyst ,  *allyl compound ,  *ether ,  ruthenium complex ,  reaction mechanism ,  reaction intermediate ,  density functional method ,  aliphatic alcohol ,  unsaturated alcohol ,  cycloalkene ,  conjugated diene ,  sulfonic acid ,  aromatic compound
Semi thesaurus term： leaving group ,  chiral complex ,  chiral catalyst ,  Tsuji-Trost reaction ,  DFT calculation

Author keywords (3)： Tsuji-Trost reaction ,  Ruthenium/Bronsted acid hybrid catalyst ,  Allyl methyl ether

JST classification (3)： Addition reaction,elimination reaction  (CF02030M) ,  Catalytic reactions(homogeneous system)  (CB06090Q) ,  Alkenes  (CF03030T)

Substance index (12)： Methyl allyl ether ,  Allyl phenyl ether ,  Acetic acid allyl ,  Allyl alcohol ,  Cyclopentadiene ,  p-Toluenesulfonic acid ,  2,2-Dimethyl-1,3-dioxane-4,6-dione ,  2,3:9,8-Bis(2,2-diisopropyl-1,3-dioxolane-4,5-diylmethylene)-3,8-dihydronaphtho[1,2-d:7,8-d′]diimidazole ,  N-[2-[2-(3-Methoxy-1-propenyl)phenyl]ethyl]-4-methylbenzenesulfonamide ,  1-Vinyl-2-tosyl-1,2,3,4-tetrahydroisoquinoline ,  1-Phenyl-3-methoxy-1-propene ,  2,2-Dimethyl-5β-[(R)-1-phenylallyl]-1,3-dioxane-4,6-dione

Reference (49)：

• 1) Reports in the earlier stage: a) J. Tsuji, H. Takahashi, M. Morikawa, Tetrahedron Lett. 1965, 6, 4387.
• 1) b) K. E. Atkins, E. E. Waiker, R. M. Manyik, Tetrahedron Lett. 1970, 11, 3821.
• 1) c) G. Hata, K. Takahashi, A. Miyake, J. Chem. Soc. D 1970, 1392.
• 1) d) K. Takahashi, A. Miyake, G. Hata, Bull. Chem. Soc. Jpn. 1972, 45, 230.
• 1) e) B. M. Trost, T. J. Fullerton, J. Am. Chem. Soc. 1973, 95, 292.

Terms in the title (7)： 触媒 ,  アリル化 ,  アリル ,  性転換 ,  堅牢 ,  アリルメチルエーテル ,  有用性