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J-GLOBAL ID：201702243533592959   Reference number：17A0599939

RHODIUM(I)-CATALYZED SILYLATION OF ARYL IODIDES WITH DI(2-FURYL)METHYLSILANE

ジ(2-フリル)メチルシランによるアリールヨージドのロジウム(I)接触シリル化

Author (6)： KOHARI Yoshihito (Kitami Inst. of Technol., Hokkaido, JPN) ,  KANO Yusuke (Kitami Inst. of Technol., Hokkaido, JPN) ,  MATSUOKA Yusuke (Kitami Inst. of Technol., Hokkaido, JPN) ,  NAMIKOSHI Takeshi (Kitami Inst. of Technol., Hokkaido, JPN) ,  WATANABE Shinji (Kitami Inst. of Technol., Hokkaido, JPN) ,  MURATA Miki (Kitami Inst. of Technol., Hokkaido, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 95  Issue： 1  Page： 152-157  Publication year： Jan. 25, 2017 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,  catalytic reaction ,  rhodium catalyst ,  rhodium complex ,  *silylation ,  aromatic iodine compound ,  *silanes ,  *organosilicon compound ,  oxygen heterocyclic compound ,  reaction mechanism ,  density functional method
Semi thesaurus term： furans ,  catalytic cycle

JST classification (2)： Organosilicon compounds  (CF08030C) ,  Catalytic reactions in general  (CB06080F)

Substance index (9)： 3-[Methylbis(2-furyl)silyl]benzonitrile ,  4′-[Methylbis(2-furyl)silyl]acetophenone ,  4-[Methylbis(2-furyl)silyl]benzoic acid ethyl ester ,  1-Iodo-4-methoxybenzene ,  Methyldi(2-furanyl)2-methoxyphenylsilane ,  Methyldi(2-furanyl)4-methoxyphenylsilane ,  Methylbis(2-furyl)[4-(trifluoromethyl)phenyl]silane ,  Methylbis(2-furyl)silane ,  Methylbis(2-furyl)phenylsilane

Reference (11)：

• For books, see: (a) E. W. Colvin, 'Silicon Reagents in Organic Synthesis,' Academic Press, London, 1988; (b) 'Chemistry of Organosilicon Compounds,' Vol. 3, ed. by Z. Rappoport and Y. Apeloig, Wiley-VCH, New York, 2001.
• For reviews, see: (a) Y. Nakao and T. Hiyama, Chem. Soc. Rev., 2011, 40, 4893; (b) H. F. Sore, W. R. J. D. Galloway, and D. R. Spring, Chem. Soc. Rev., 2012, 41, 1845.
• For selected examples, see: (a) K. Itami, T. Nokami, and J. Yoshida, J. Am. Chem. Soc. , 2001, 123, 5600; (b) K. Itami, T. Nokami, Y. Ishimura, K. Mitsudo, T. Kamei, and J. Yoshida, J. Am. Chem. Soc., 2001, 123, 11577; (c) K. Hosoi, K. Nozaki, and T. Hiyama, Chem. Lett., 2002, 31, 138.
• M. Murata, H. Ohara, R. Oiwa, S. Watanabe, and Y. Masuda, Synthesis, 2006, 1771.
• For reviews, see: (a) Y. Yamanoi and H. Nishihara, Yuki Gosei Kagaku Kyokaishi, 2009, 67, 778; (b) M. Murata and Y. Masuda, Yuki Gosei Kagaku Kyokaishi, 2010, 68, 845; (c) M. Murata, 'Science of Synthesis Reference Library: Cross-Coupling and Heck-type Reactions,' Vol. 2, ed. by J. P Wolfe, Thieme, Stuttgart, 2012, pp. 439-483.

Terms in the title (4)： フリル ,  メチルシラン ,  ロジウム ,  シリル化