Art

J-GLOBAL ID：201702244119403409   Reference number：17A0918761

First Detection of Unprotected 1,2-Anhydro Aldopyranoses

非保護1,2-アンヒドロアルドピラノース

Author (4)： Serizawa Kazunari (Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University) ,  Noguchi Masato (Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University) ,  Li Gefei (Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University) ,  Shoda Shin-ichiro (Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University)
Material： Chemistry Letters  (Chem Lett)
Volume： 46  Issue： 7  Page： 1024-1026(J-STAGE)  Publication year： 2017 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *anhydro sugar ,  carbohydrate ,  chemical reaction ,  *dehydration reaction ,  *13C NMR ,  *proton magnetic resonance ,  detection ,  *COSY ,  intramolecular reaction ,  carbohydrate ,  hexose ,  aldose
Semi thesaurus term： saccharide

Author keywords (3)： Unprotected 12-anhydro sugar ,  Aldopyranose ,  Low-temperature NMR spectroscopy

JST classification (3)： Monosaccharides  (CF10052H) ,  Magnetic resonance of organic molecules  (BH06073K) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (4)： Glucose ,  2-Chloro-1,3-dimethylimidazolium chloride ,  CDMBI ,  1,2-Anhydro-α-D-glucopyranose

Reference (28)：

• 1) P. Brigl, Hoppe-Seyler’s Z. Physiol. Chem. 1922, 122, 245.
• 2) a) R. U. Lemieux, Can. J. Chem. 1953, 31, 949.
• 2) b) R. U. Lemieux, G. Huber, J. Am. Chem. Soc. 1953, 75, 4118.
• 3) R. L. Halcomb, S. J. Danishefsky, J. Am. Chem. Soc. 1989, 111, 6661.
• 4) A. Pictet, P. Castan, Helv. Chim. Acta 1920, 3, 645.