Art

J-GLOBAL ID：201702250097165391   Reference number：17A0898177

A Facile Synthesis of N-Alkoxyacylimidoyl Halides from α-Nitro Ketones and Alkyl Halides in the Presence of NaHSO₄/SiO₂

NaHSO₄/SiO₂存在下におけるα-ニトロケトン類とハロゲン化アルキルからのN-アルコキシアシルイミドイルハライドの容易な合成

Author (6)： AOYAMA Tadashi (Nihon Univ., Tokyo, JPN) ,  ITOH Ken-ichi (Nihon Univ., Chiba, JPN) ,  FURUKAWA Yuri (Nihon Univ., Tokyo, JPN) ,  HAYAKAWA Mamiko (Nihon Univ., Tokyo, JPN) ,  SHIMADA Shigeru (National Inst. of Advanced Industrial Sci. and Technol. (AIST), Ibaraki, JPN) ,  OUCHI Akihiko (Nihon Univ., Tokyo, JPN)
Material： Synlett
Volume： 28  Issue： 4  Page： 489-493  Publication year： Mar. 01, 2017 
JST Material Number： W0113A  ISSN： 0936-5214  CODEN： SYNLES  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *imide ,  nitrile oxide ,  one-pot synthesis ,  stereoselectivity ,  halide ,  supported catalyst ,  hydrogensulfate ,  ORTEP diagram ,  molecular structure ,  reaction mechanism ,  NMR ,  aliphatic halogen compound ,  ketone ,  acid catalytic reaction ,  *condensation reaction
Semi thesaurus term： *imides ,  alkyl halide ,  solid acid catalysis ,  sodium hydrogensulfate

JST classification (2)： Nitrogen derivatives of aromatic monocyclic carboxylic acids  (CF05200S) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (15)： 4-Methyl-α-(tert-butoxyimino)phenacyl bromide ,  tert-Butoxyimino(bromo)methyl(4-methoxyphenyl) ketone ,  4-Bromo-α-(tert-butoxyimino)phenacyl bromide ,  tert-Butoxyimino(bromo)methyl(4-nitrophenyl) ketone ,  tert-Butoxyimino(bromo)methyl(2-naphthyl) ketone ,  tert-Butoxyimino(bromo)methyl(2-thienyl) ketone ,  tert-Butoxyimino(bromo)methyl(5-methyl-2-thienyl) ketone ,  tert-Butoxyimino(bromo)methyl(5-bromo-2-thienyl) ketone ,  tert-Butoxyimino(bromo)methyl(benzyl) ketone ,  1-Bromo-1-(tert-butoxyimino)octane-2-one ,  α-(tert-Butoxyimino)phenacyl bromide ,  α-Chloro-α-(tert-butoxyimino)acetophenone ,  α-Iodo-α-(tert-butoxyimino)acetophenone ,  1,1-Dimethylpropoxyimino(bromo)methylphenyl ketone ,  Diphenylmethoxyimino(bromo)methylphenyl ketone

Terms in the title (3)： SiO2 ,  ケトン類 ,  ハロゲン化アルキル