Art

J-GLOBAL ID：201702264043629084   Reference number：17A1013333

Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates

フェニル(ペルフルオロアルキル)ヨードニウムトリフラート類を使用するアルキン類の位置および立体選択的ペルフルオロアルキルトリフラート化

Author (2)： WANG Xi (Univ. Muenster, Muenster, DEU) ,  STUDER Armido (Univ. Muenster, Muenster, DEU)
Material： Organic Letters  (Org Lett)
Volume： 19  Issue： 11  Page： 2977-2980  Publication year： Jun. 02, 2017 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： acetylenic compound ,  alkylation ,  *esterification ,  copper chloride ,  copper catalyst ,  regiospecific reaction ,  stereospecific reaction ,  aromatic iodine compound ,  *addition reaction
Semi thesaurus term： *perfluoroalkylation ,  *トリフラート化 ,  *hypervalent iodine compound

JST classification (2)： Aliphatic halogen compounds  (CF03050P) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (17)： 4-(1-Pentyne-1-yl)benzoic acid ethyl ester ,  Trifluoromethanesulfonic acid (phenyl(propyl) iodine(III)) salt ,  4-((E)-1-Trifluoromethylsulfonyloxy-2-propyl-3,3,4,4,5,5,5-heptafluoro-1-pentenyl)benzoic acid ethyl ester ,  Trifluoromethanesulfonic acid (1-(4-cyanophenyl)-2-propyl-3,3,4,4,5,5,5-heptafluoro-1-pentenyl) ester ,  Trifluoromethanesulfonic acid (1-(4-acetylphenyl)-2-propyl-3,3,4,4,5,5,5-heptafluoro-1-pentenyl) ester ,  Trifluoromethanesulfonic acid (1-(4-methylsulfonylphenyl)-2-propyl-3,3,4,4,5,5,5-heptafluoro-1-pentenyl) ester ,  Trifluoromethanesulfonic acid (1-(4-tosyloxyphenyl)-2-propyl-3,3,4,4,5,5,5-heptafluoro-1-pentenyl) ester ,  Trifluoromethanesulfonic acid (1-(3,5-dibromophenyl)-2-propyl-3,3,4,4,5,5,5-heptafluoro-1-pentenyl) ester ,  4-((E)-1-Trifluoromethylsulfonyloxy-2-methyl-3,3,4,4,5,5,5-heptafluoro-1-pentenyl)benzoic acid ethyl ester ,  (E)-2-(Heptafluoropropyl)-3-trifluoromethylsulfonyloxy-3-(4-ethoxycarbonylphenyl)acrylic acid methyl ester ,  4-((E)-1-Trifluoromethylsulfonyloxy-2-propyl-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-octenyl)benzoic acid ethyl ester ,  4-((E)-1-(4-Methoxyphenyl)-2-propyl-3,3,4,4,5,5,5-heptafluoro-1-pentene-1-yl)benzonitrile ,  4,4′-((1E,3Z)-1-Phenyl-5,5,6,6,7,7,8,8,8-nonafluoro-1,3-octadiene-3,4-diyl)bis(benzoic acid ethyl) ester ,  4,4′-((E)-8,8,9,9,10,10,10-Heptafluoro-6-decene-4-yne-6,7-diyl)bis(benzoic acid ethyl) ester ,  4,4′-((E)-1-Oxo-1-methoxy-4,4,5,5,6,6,7,7,7-nonafluoro-2-heptene-2,3-diyl)bis(benzoic acid ethyl) ester ,  (E)-1-Trifluoromethylsulfonyloxy-1,2-diphenyl-3,3,4,4,4-pentafluoro-1-butene ,  2-(4-((E)-1,2-Diphenyl-3,3,4,4,4-pentafluoro-1-butenyl)phenoxy)ethyldimethylamine

Terms in the title (3)： フェニル ,  ペルフルオロアルキル ,  立体