Art
J-GLOBAL ID：201702267604702385   Reference number：17A1360467

A study on an unusual SN2 mechanism in the methylation of benzyne through nickel-complexation

ニッケル錯体生成によるベンザインのメチル化における異常なSN2機構に関する研究【Powered by NICT】
Author (7)：
Hatakeyama Makoto

About Hatakeyama Makoto

(Nakamura Laboratory, RIKEN Innovation Center, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan. hatakeyama_xeno@riken.jp)

About Nakamura Laboratory, RIKEN Innovation Center, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan. hatakeyama_xeno@riken.jp

, 
Sakamoto Yuki

About Sakamoto Yuki

, 
Ogata Koji

About Ogata Koji

, 
Sumida Yuto

About Sumida Yuto

, 
Sumida Tomoe

About Sumida Tomoe

, 
Hosoya Takamitsu

About Hosoya Takamitsu

, 
Nakamura Shinichiro

About Nakamura Shinichiro


Material：
Physical Chemistry Chemical Physics  (PCCP)

About Physical Chemistry Chemical Physics


Volume： 19  Issue： 39  Page： 26926-26933  Publication year： 2017 
JST Material Number： A0271C  ISSN： 1463-9076  CODEN： PPCPFQ  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)
Abstract/Point：
Abstract/Point
Japanese summary of the article(about several hundred characters).
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In this study, three reaction ...
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Thesaurus term：
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Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
*Methylation

About Methylation

, 
*nickel complex

About nickel complex

, 
*SN2 type reaction

About SN2 type reaction

, 
metathesis

About metathesis

, 
concerted reaction

About concerted reaction

, 
cleavage reaction

About cleavage reaction

, 
addition reaction

About addition reaction

, 
elimination reaction

About elimination reaction

, 
oxidation-reduction reaction

About oxidation-reduction reaction

, 
density functional method

About density functional method

, 
potential barrier

About potential barrier

, 
organometallic compound

About organometallic compound

, 
valence

About valence

, 
steric hindrance

About steric hindrance

, 
iodination

About iodination

, 
reaction mechanism

About reaction mechanism

, 
metallacycle

About metallacycle

, 
aliphatic iodine compound

About aliphatic iodine compound

, 
organic compound

About organic compound


JST classification (3)：
JST classification
Category name(code) classified by JST.
Addition reaction,elimination reaction 
(CF02030M)

About Addition reaction,elimination reaction

,  Cyclohexanes 
(CF04050W)

About Cyclohexanes

,  Cobalt bnd nickel complexes 
(CE01092Y)

About Cobalt bnd nickel complexes

Terms in the title (6)：
Terms in the title
Keywords automatically extracted from the title.
ニッケル

About ニッケル

, 
錯体生成

About 錯体生成

, 
ベンザイン

About ベンザイン

, 
メチル化

About メチル化

, 
SN2機構

About SN2機構

, 
研究

About 研究


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