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J-GLOBAL ID：201702269258557554   Reference number：17A0565814

Remarkably Stable S-Oxides of Calix[4]thiophenes and Their Sulfonium Ylide from Reaction of S-Oxide with Acetylene Derivative

カリックス[4]チオフェン類の著しく安定なS-オキシド及びそのS-オキシドとアセチレン誘導体の反応からのスルホニウム誘導体

Author (3)： Takeuchi Noritaka (Department of Applied Chemistry, Kindai University) ,  Nakahodo Tsukasa (Department of Applied Chemistry, Kindai University) ,  Fujihara Hisashi (Department of Applied Chemistry, Kindai University)
Material： Chemistry Letters  (Chem Lett)
Volume： 46  Issue： 3  Page： 389-391(J-STAGE)  Publication year： 2017 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *sulfur heterocyclic compound ,  *bridged compound ,  *macrocyclic compound ,  *sulfoxide ,  acetylenic compound ,  *sulfonium ,  cycloaddition ,  crystal structure ,  X-Ray Diffraction ,  *oxidation ,  Thiophenes

Author keywords (3)： Calixarene ,  Macrocyclic thiophene ,  X-ray crystallography

JST classification (2)： Eight or more-membered heterocyclic compounds  (CF07120T) ,  Oxidation,reduction  (CF02060T)

Substance index (8)： 2-Butynedioic acid dimethyl ,  m-Chloroperbenzoic acid ,  2,2,7,7,12,12,17,17-Octaethyl-21,22,23,24-tetrathiapentacyclo[16.2.1.1^3,6.1^8,11.1^13,16]tetracosa-1(20),3,5,8,10,13,15,18-octaene 21-oxide ,  2,2,7,7,12,12,17,17-Octaethyl-21,22,23,24-tetrathiapentacyclo[16.2.1.1^3,6.1^8,11.1^13,16]tetracosa-1(20),3,5,8,10,13,15,18-octaene 21,23-dioxide ,  2,5-[Thiophene-2,5-diylbis[cyclooctane-1,1-diyl(thiophene-2,5-diyl)(cyclooctane-1,1-diyl)]]thiophene 1-oxide ,  Tetraspiro[21,22,23,24-tetrathiapentacyclo[16.2.1.1^3,6.1^8,11.1^13,16]tetracosa-1(20),3,5,8,10,13,15,18-octaene-2,1′:7,1′′:12,1′′′:17,1′′′′-tetracyclooctane]21,21,22,22,23,23,24,24-octaoxide ,  2-[[2,2,7,7,12,12,17,17-Octaethyl-21,22,23,24-tetrathiapentacyclo[16.2.1.1^3,6.1^8,11.1^13,16]tetracosa-1(20),3,5,8,10,13,15,18-octaene-21-cation]-21-yl]-4-hydroxy-1-methoxy-1,3,4-trioxobutane-2-ide ,  2-[[2,2,7,7,12,12,17,17-Octaethyl-21,22,23,24-tetrathiapentacyclo[16.2.1.1^3,6.1^8,11.1^13,16]tetracosa-1(20),3,5,8,10,13,15,18-octaene-21-cation]-21-yl]-1,4-dimethoxy-1,3,4-trioxobutane-2-ide

Reference (25)：

• 1) C. D. Gutsche, Calixarenes: An Introduction, RSC Publishing, 2008. doi:10.1039/9781847558190;
• 1) W. Sliwa, C. Kozlowski, Calixarenes and Resorcinarenes, Wiley-VCH, 2009;
• 1) Calixarenes and Beyond, ed. by P. Neri, J. L. Sessler, M.-X. Wang, Springer, 2016. doi:10.1007/978-3-319-31867-7.
• 2) K. A. Nielsen, W.-S. Cho, J. O. Jeppesen, V. M. Lynch, J. Becker, J. L. Sessler, J. Am. Chem. Soc. 2004, 126, 16296;
• 2) J. Bachmann, D. G. Nocera, J. Am. Chem. Soc. 2005, 127, 4730.

Terms in the title (5)： チオフェン類 ,  オキシド ,  アセチレン ,  誘導体 ,  スルホニウム