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J-GLOBAL ID：201702274690733833   Reference number：17A0868190

Multinuclear zinc bisamidinate catalyzed asymmetric alkylation of α-ketoesters and its unique chemoselectivity

多核亜鉛ビスアミジナートを触媒とするα-ケトエステル類の不斉アルキル化とそのユニークな化学選択性【Powered by NICT】

Author (5)： Yamanaka Masahiro (Department of Chemistry and Research Center for Smart Molecules, Rikkyo University, 3-34-1 Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan. [e-mail]) ,  Inaba Masamitsu ,  Gotoh Ryo ,  Ueki Yoshiyuki ,  Matsui Kenichiro
Material： Chemical Communications  (ChemComm)
Volume： 53  Issue： 54  Page： 7513-7516  Publication year： 2017 
JST Material Number： D0376B  ISSN： 1359-7345  CODEN： CHCOFS  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Abstract/Point： The multinuclear Zn-bisamidina...

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Thesaurus term： *zinc compound ,  *transition metal catalyst ,  catalytic reaction ,  *asymmetric synthesis ,  *alkylation ,  *keto ester ,  imide ,  cyanamide ,  zinc complex ,  *alcohol
Semi thesaurus term： Amidines ,  *zinc catalyst ,  chemoselective reaction

JST classification (6)： Complexes of 9 and 10 groups  (CE01050Y) ,  Nitrogen derivatives of aliphatic carboxylic acids  (CF03220A) ,  Aliphatic amines,imines,quaternary ammonium,immonium compounds  (CF03070L) ,  Aromatic monocyclic ketones  (CF05170I) ,  Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P) ,  Aliphatic alcohols  (CF03090H)

Substance index (4)： 1β,2α-Bis[[1-(anthracene-9-ylamino)ethylidene]amino]cyclohexane ,  (R)-2-Cyclohexyl-2-hydroxybutanoic acid methyl ester ,  (R)-2-Hydroxy-2-(2-methoxyphenyl)butanoic acid methyl ester ,  (R)-2-Hydroxy-2-[2-(methylthio)phenyl]butanoic acid methyl ester

Terms in the title (5)： 亜鉛 ,  触媒 ,  ケトエステル ,  アルキル化 ,  化学選択性