Art

J-GLOBAL ID：201702275956453953   Reference number：17A0786046

Synthesis of trans,trans,cis-fused tetracyclic skeleton via radical domino cyclization

ラジカルドミノ環化を経るtrans,trans,cis-縮合四環系骨格の合成

Author (4)： Furuta Miyu (Department of Pharmaceutical Sciences, Faculty of Pharmacy, Keio University, 1-5-30 Shibakoen, Minato-ku, Tokyo 105-8512, Japan) ,  Hanaya Kengo (Department of Pharmaceutical Sciences, Faculty of Pharmacy, Keio University, 1-5-30 Shibakoen, Minato-ku, Tokyo 105-8512, Japan) ,  Sugai Takeshi (Department of Pharmaceutical Sciences, Faculty of Pharmacy, Keio University, 1-5-30 Shibakoen, Minato-ku, Tokyo 105-8512, Japan) ,  Shoji Mitsuru (Department of Pharmaceutical Sciences, Faculty of Pharmacy, Keio University, 1-5-30 Shibakoen, Minato-ku, Tokyo 105-8512, Japan)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 73  Issue： 16  Page： 2316-2322  Publication year： Apr. 20, 2017 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *limonoid ,  radical reaction ,  *cyclization reaction ,  *consecutive reaction ,  alicyclic ketone ,  asymmetric synthesis ,  polyene ,  catalytic reaction ,  *free-radical cyclization ,  *Fused-Ring Compounds ,  cascade reaction
Semi thesaurus term： domino reaction

Author keywords (5)： Limonoid ,  Tetracyclic core ,  Domino cyclization ,  Radical cyclization ,  Stereoselective

JST classification (2)： Carotenoids,other terpenoids  (CF10025Z) ,  Condensed tetra-or more-cyclic carbocyclic compounds  (CF06090C)

Substance index (5)： Mesendanin L ,  12-Hydroxyamoorastatone ,  Meliatoosenin F ,  rel-(2E,6Z,9R^*,10Z,14E,19S^*)-7-[(Benzyloxy)methyl]-9-(benzyloxy)-11-cyano-15-methyl-18-oxo-19-chloroicosa-2,6,10,14-tetraenedioic acid dimethyl ester ,  rel-(13S^*)-3-Oxo-4-chloro-8-cyano-11β,18-bis(benzyloxy)-17-(2-methoxy-2-oxoethylidene)-5α-androstane-4-carboxylic acid methyl ester

Terms in the title (5)： 環化 ,  CIS ,  縮合 ,  環 ,  骨格