Art

J-GLOBAL ID：201702278085002854   Reference number：17A0868611

Copper(I)-Catalyzed Enantioselective Boryl Substitution of Allyl Acylals: An Efficient Approach for Enantioenriched α-Chiral γ-Acetoxyallylboronates

銅(I)触媒によるアリルアシラール類のエナンチオ選択的ボリル置換反応:エナンチオ豊富なα-キラルγ-アセトキシアリルボロン酸エステル類のための効率的な方法

Author (4)： TAKENOUCHI Yuta (Hokkaido Univ., Hokkaido, JPN) ,  KOJIMA Ryoto (Hokkaido Univ., Hokkaido, JPN) ,  MOMMA Riko (Hokkaido Univ., Hokkaido, JPN) ,  ITO Hajime (Hokkaido Univ., Hokkaido, JPN)
Material： Synlett
Volume： 28  Issue： 2  Page： 270-274  Publication year： Jan. 24, 2017 
JST Material Number： W0113A  ISSN： 0936-5214  CODEN： SYNLES  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *stereoselectivity ,  copper catalyst ,  copper complex ,  catalytic reaction ,  allylation ,  acylal ,  allyl compound ,  *substitution reaction ,  *ester ,  *organic boron acid ,  asymmetric reaction ,  addition reaction
Semi thesaurus term： *enantioselectivity ,  *boronic acid ester ,  transition metal catalyzed reaction

JST classification (3)： Stereochemistry of organic reaction  (CF02130V) ,  Substitution reaction  (CF02020B) ,  Organoboron compounds  (CF08020R)

Substance index (13)： (1E,3S)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-5-phenyl-1-pentene-1-ol acetate ,  (1Z,3S)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-5-phenyl-1-pentene-1-ol acetate ,  (1E,3S)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-butene-1-ol acetate ,  (1E,3S)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-nonene-1-ol acetate ,  (1E,3S)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-4-cyclopentyl-1-butene-1-ol acetate ,  (1E,3S)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-5-(tert-butyldimethylsiloxy)-1-pentene-1-ol acetate ,  (1E,3R)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-octene-1-ol acetate ,  (1E)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-3-methyl-1-methoxy-1-butene ,  (1E)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-3-methyl-1-butene-1-ol acetate ,  (3E,5R,6S)-1-(tert-Butyldiphenylsiloxy)-5-acetoxy-3-tridecene-7-yne-6-ol ,  (3E,5R,6S)-1-(tert-Butyldiphenylsiloxy)-3-tridecene-7-yne-5,6-diol ,  (2Z)-1,1-Di(benzyloxy)-4-cyclohexyl-2-butene ,  (2Z)-1,1-Diacetoxy-4-cyclopentyl-2-butene

Terms in the title (6)： 銅 ,  触媒 ,  置換反応 ,  キラル ,  酸 ,  エステル類