Art

J-GLOBAL ID：201702281745960627   Reference number：17A1475023

Ru(0)-catalyzed C3-selective Coupling Reactions of Unsaturated 5-Membered Heterocycles with Methyl Methacrylate and Methacryl Amide

不飽和5員複素環化合物とメタクリル酸メチル及びメタクリルアミドとのRu(0)触媒C3選択的カップリング反応

Author (4)： Hirano Masafumi (Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology) ,  Moritake Masahiro (Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology) ,  Murakami Tasuku (Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology) ,  Komine Nobuyuki (Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology)
Material： Chemistry Letters  (Chem Lett)
Volume： 46  Issue： 10  Page： 1522-1524(J-STAGE)  Publication year： 2017 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *oxygen heterocyclic compound ,  *nitrogen heterocyclic compound ,  *ruthenium complex ,  *ruthenium catalyst ,  *coupling reaction ,  *selectivity ,  unsaturated fatty acid ,  pesticide ,  chemical compound ,  yield ,  *olefin compound ,  *carboxylate(ester) ,  *aliphatic carboxylic acid ,  *unsaturated carboxylic acid ,  *carboxamide ,  sulfone ,  sulfur heterocyclic compound ,  polyacene
Semi thesaurus term： lead compound

Author keywords (3)： C3-selective coupling ,  Ruthenium ,  Pesticide lead

JST classification (4)： Addition reaction,elimination reaction  (CF02030M) ,  Furans  (CF07072V) ,  Nitrogen derivatives of aliphatic carboxylic acids  (CF03220A) ,  Catalytic reactions(homogeneous system)  (CB06090Q)

Substance index (10)： 2,5-Dihydrofuran ,  3-Pyrroline ,  2,5-Dihydrothiophene 1,1-dioxide ,  Naphthalene ,  Methacrylamide ,  Methacrylic acid methyl ,  1-Tosyl-3-pyrroline ,  Bicyclo[3.3.1]nona-2,6-diene ,  2-Methyl-3-(tetrahydrofuran-3-yl)propanamide ,  2-Methyl-3-(tetrahydrofuran-3-yl)propeneamide

Reference (15)：

• 1) a) H. Wynberg, J. Am. Chem. Soc. 1958, 80, 364.
• 1) b) C. Botteghi, G. Consiglio, G. Ceccarelli, A. Stefani, J. Org. Chem. 1972, 37, 1835.
• 1) c) Z. Şahin, N. Gürbüz, Ì. Özdemir, O. Şahin, O. Büyükgüngör, M. Achard, C. Bruneau, Organometallics 2015, 34, 2296.
• 2) T. Morita, M. Akita, T. Satoh, F. Kakiuchi, M. Miura, Org. Lett. 2016, 18, 4598.
• 3) M. Hirano, Y. Hiroi, T. Murakami, H. Ogawa, S. Kiyota, N. Komine, S. Komiya, Organometallics 2016, 35, 1343.

Terms in the title (8)： 不飽和 ,  複素環化合物 ,  メタクリル酸メチル ,  メタクリルアミド ,  Ru ,  触媒 ,  C3 ,  カップリング反応